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a, \(n_{KOH}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PT: \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{KOH}=0,15\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\)
b, \(n_{Na_2CO_3}=0,2.0,5=0,1\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,1}{1}\), ta được Na2CO3 dư.
Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{CH_3COOH}=0,075\left(mol\right)\Rightarrow V_{CO_2}=0,075.22,4=1,68\left(l\right)\)
\(n_{Na_2O}=\dfrac{6,2}{62}=0,1 \left(mol\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,1 -----------------> 0,1
\(CM_{base}=CM_{NaOH}=\dfrac{0,1}{0,2}=0,5M\)
b
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,05 <------ 0,1
\(V_{H_2SO_4}=\dfrac{0,05}{0,2}=0,25\left(l\right)\Rightarrow V_{dd.H_2SO_4}=\dfrac{0,25.100}{20}=1,25\left(l\right)\)
a, \(n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Mg}=0,1.24=2,4\left(g\right)\)
\(V=V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH}=n_{CH_3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
\(\Rightarrow V_{ddC_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\)
Ta có:
n HCL = 0,4 ( mol )
n Na2SO3 = 0,25 ( mol )
PTHH
Na2SO3 + 2HCL \(\rightarrow\) 2NaCL + SO2 + H2O
0,2----------0,4-------------------0,2
theo pthh: n Na2SO3 phản ứng = 0,2 ( mol )
=> n Na2SO3 dư = 0,05 ( mol )
a)
SO2 + Br2 + 2H2O \(\rightarrow\) H2SO4 + 2HBr
0,2-----0,2
theo pthh: n Br2 = 0,2 ( mol ) => m Br2 = 32 ( g )
b)
PTHH
Na2SO3 + Ba(OH)2 \(\rightarrow\) BaSO3 + 2NaOH
0,05-------------------------0,05
theo pthh: n BaSO3 = 0,05 ( mol ) => m BaSO3 = 10,85 ( g )
\(n_{Al\left(OH\right)_3}=\dfrac{15,6}{78}=0,2\left(mol\right)\)
\(n_{AlCl_3}=0,2.1,5=0,3\left(mol\right)\)
PTHH: \(3NaOH+AlCl_3\rightarrow3NaCl+Al\left(OH\right)_3\)
0,9<-----0,3-------------------->0,3
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)
0,1<------0,1
=> nNaOH max = 1 (mol)
=> \(V_{dd}=\dfrac{1}{0,5}=2\left(l\right)\)
\(n_{CH_3COOH}=\dfrac{300\cdot5\%}{60}=0.25\left(mol\right)\)
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(0.25........................................................0.125\)
\(V_{H_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(n_{C_2H_5OH}=0.1\cdot2=0.2\left(mol\right)\)
\(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\left(ĐK:H_2SO_{4\left(đ\right)},t^0\right)\)
\(0.2......................0.2.....................0.2\)
\(\Rightarrow CH_3COOHdư\)
\(m_{CH_3COOC_2H_5}=0.2\cdot88=17.6\left(g\right)\)
a) n CH3COOH = 300.5%/60 = 0,25(mol)
Zn + 2CH3COOH $\to$ (CH3COO)2Zn + H2
Theo PTHH :
n H2 = 1/2 n CH3COOH = 0,25/2 = 0,125(mol)
V H2 = 0,125.22,4 = 2,8(lít)
b) n C2H5OH = 0,1.2 = 0,2(mol)
\(CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\)
Ta thấy :
n CH3COOH = 0,25 > n C2H5OH = 0,2 => CH3COOH dư
n CH3COOC2H5 = n C2H5OH = 0,2 mol
=> m CH3COOC2H5 = 0,2.88 = 17,6 gam
