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a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,2--------->0,4--------------->0,4------->0,2
=> VCO2 = 0,2.22,4 = 4,48 (l)
b) \(m_{dd.CH_3COOH}=\dfrac{0,4.60}{12\%}=200\left(g\right)\)
c) mdd sau pư = 21,2 + 200 - 0,2.44 = 212,4 (g)
=> \(C\%_{muối}=\dfrac{0,4.82}{212,4}.100\%=15,44\%\)
Câu 8 :
\(n_{MgCO3}=\dfrac{42}{84}=0,5\left(mol\right)\)
Pt : \(2CH_3COOH+MgCO_3\rightarrow\left(CH_3COO\right)_2Mg+CO_2+H_2O\)
1 0,5 0,5
a) \(V_{CO2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
b) \(V_{CH3COOH}=\dfrac{1}{2}=0,5\left(l\right)\)
c) Pt : \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
1 1
300ml = 0,3l
\(C_{MCH3COONa}=\dfrac{1}{0,3}=\dfrac{10}{3}\left(M\right)\)
Chúc bạn học tốt
nNaOH = 0,1.2 = 0,2 (mol)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,2<--------0,2
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)
nNaOH = 0,1 . 2 = 0,2 (mol)
PTHH: CH3COOH + NaOH -> CH3COONa + H2O
nCH3COOH = nNaOH = 0,2 (mol)
CM(CH3COOH) = 0,2/0,15 = 1,33M
CH3COOH + NaOH => CH3COONa + H2O
500 ml dd = 0.5 l dd
mNaOH = 20x30/100 = 6 (g)
nNaOH = m/M = 6/40 = 0.15 (mol)
Theo phương trình => nCH3COOH = 0.15 (mol)
CM dd CH3COOH = n/V = 0.15/0.5 = 0.3M
2CH3COOH + Na2CO3 => 2CH3COONa + CO2 + H2O
nNa2CO3 = 0.5x0.2 = 0.1 (mol)
Theo phương trình ==> nCO2 = 0.1 (mol)
VCO2 = n x 22.4 = 0.1 x 22.4 = 2.24 (l)
\(a,Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b,n_{CH_3COOH}=2.0,2=0,4\left(mol\right)\\ C_{MddCH_3COOH}=\dfrac{0,4}{0,4}=1\left(M\right)\\ c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\\ n_{CH_3COOK}=n_{CH_3COOH}=0,4\left(mol\right)\\ V_{ddCH_3COOK}=400+400=800\left(ml\right)=0,8\left(l\right)\\ C_{MddCH_3COOK}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
0,4 0,2
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(b,C_{M_{CH_3COOH}}=\dfrac{0,4}{0,4}=1M\)
\(c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,4 0,4 0,4
\(C_{M_{CH_3COOK}}=\dfrac{0,4}{0,4}=1M\)
a, \(n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Mg}=0,1.24=2,4\left(g\right)\)
\(V=V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH}=n_{CH_3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
\(\Rightarrow V_{ddC_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\)
\(a,n_{CH_3COOH}=\dfrac{120.20}{100}=24\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{24}{60}=0,4\left(mol\right)\)
PTHH: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2\uparrow+H_2O\)
0,4----------->0,2-------------->0,4-------------->0,2
\(\rightarrow m_{ddNa_2CO_3}=\dfrac{0,2.106}{10\%}=212\left(g\right)\)
\(\rightarrow m_{ddA}=212+120-0,2.44=323,2\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{0,4.82}{323,2}.100\%=10,15\%\)
b, PTHH: \(C_2H_5OH+O_2\underrightarrow{\text{men giấm}}CH_3COOH+H_2O\)
0,4<------------------------0,4
\(\rightarrow V_{ddC_2H_5OH}=\dfrac{0,4.46.100}{0,8.46}=50\left(ml\right)\)
a, \(n_{KOH}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PT: \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{KOH}=0,15\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\)
b, \(n_{Na_2CO_3}=0,2.0,5=0,1\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,1}{1}\), ta được Na2CO3 dư.
Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{CH_3COOH}=0,075\left(mol\right)\Rightarrow V_{CO_2}=0,075.22,4=1,68\left(l\right)\)