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nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
a) nBaSO4=0,1(mol)
PTHH: Ba(OH)2 + H2SO4 -> BaSO4 + 2 H2O
2 NaOH + H2SO4 -> Na2SO4 + 2 H2O
=> nBa(OH)2= 0,1(mol) => mBa(OH)2=171.0,1=17,1(g)
%mBa(OH)2= (17,1/40).100=42,75%
=>%mNaOH=57,25%
b) mNaOH=22,9(g) => nNaOH= 22,9/40=0,5725(mol)
=> nH2SO4= 0,1+ 0,5725:2= 309/800(mol)
=>mH2SO4=309/800. 98=37,8525(g)
=>C%ddH2SO4= (37,8525/100).100=37,8525%
\(a,PTHH:Na_2O+H_2O\rightarrow2NaOH\\ \Rightarrow n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{37,2}{62}=0,6\cdot2=1,2\left(mol\right)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{1,2}{0,5}=2,4M\\ b,PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{58,8\cdot100\%}{20\%}=294\left(g\right)\\ \Rightarrow V_{dd}=\dfrac{294}{1,14}\approx257,9\left(ml\right)\)
Bài 1:
a) Na2O + H2O → 2NaOH (1)
\(n_{Na_2O}=\frac{15,5}{62}=0,25\left(mol\right)\)
Theo pT1: \(n_{NaOH}=2n_{Na_2O}=2\times0,25=0,5\left(mol\right)\)
\(\Rightarrow C_{M_{NaOH}}=\frac{0,5}{0,5}=1\left(M\right)\)
b) 2NaOH + H2SO4 → Na2SO4 + 2H2O (2)
Theo PT2: \(n_{H_2SO_4}=\frac{1}{2}n_{NaOH}=\frac{1}{2}\times0,5=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25\times98=24,5\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\frac{24,5}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\frac{122,5}{1,14}=107,46\left(ml\right)\)
c) Theo PT2: \(n_{Na_2SO_4}=n_{H_2SO_4}=0,25\left(mol\right)\)
Ta có: \(V_{dd}saupư=0,5+0,10746=0,60746\left(l\right)\)
\(C_{M_{Na_2SO_4}}=\frac{0,25}{0,60746}=0,41\left(M\right)\)
\(n_{Na_2O}=\dfrac{6,2}{62}=0,1 \left(mol\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,1 -----------------> 0,1
\(CM_{base}=CM_{NaOH}=\dfrac{0,1}{0,2}=0,5M\)
b
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,05 <------ 0,1
\(V_{H_2SO_4}=\dfrac{0,05}{0,2}=0,25\left(l\right)\Rightarrow V_{dd.H_2SO_4}=\dfrac{0,25.100}{20}=1,25\left(l\right)\)