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\(n_{H_2SO_4}=0,005.0,1=0,0005\left(mol\right)\\ \Rightarrow n_{H^+}=2.0,0005=0,001\left(mol\right)\\ n_{NaOH}=0,1.0,002=0,0002\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,003.0,1=0,0003\left(mol\right)\\ \Rightarrow n_{OH^-}=0,0002+0,0003.2=0,0008\left(mol\right)\\ H^++OH^-\rightarrow H_2O\\ Vì:\dfrac{0,0008}{1}< \dfrac{0,001}{1}\Rightarrow H^+dư\\ \left[H^+\left(dư\right)\right]=\dfrac{0,001-0,0008}{0,1+0,1}=0,001\left(M\right)\\ \Rightarrow pH=-log\left[H^+\right]=-log\left[0,001\right]=3\)
\(m=m_{Na^+}+m_{Ba^{2+}}+m_{SO_4^{2-}}=0,0002.23+0,0003.137+0,0005.96=0,0937\left(g\right)\)
\(n_{NaOH}=0,1.0,01=0,001(mol)\\ \Rightarrow n_{OH^{-}}=0,001(mol)\\ n_{HCl}=0,03.0,2=0,006(mol)\\ \Rightarrow n_{H^{+}}=0,006(mol)\\ H^{+}+OH^{-}\to H_2O\\ 0,001<0,006\\ OH^{-} hêt; H^{+} dư\\ n_{H^{+}}=0,006-0,001=0,005(mol)\\ [H^{+}]=\frac{0,005}{0,1+0,2}=\frac{1}{60}M\\ \to pH=-log(\frac{1}{60})=1,77 \)
pH=7 => trung hòa vừa đủ => nH+ =nOH,mà VH+=VOH-
=> [H+]=[OH-] => pOH=pH=2 =>pHbazo=14-2=12
nHCl=0,001 mol
H++OH−→H2OH++OH−→H2O 0,001 x
=> nH+=0,001−x=0,2.10−7nH+=0,001−x=0,2.10−7
=> x=9,9998.10^-4 => [OH-]=9,9998.10^-3
=> PH=14+log[OH]=12
\(n_{NaOH}=0,03.0,1=0,003\left(mol\right)\\ n_{HNO_3}=0,01.0,01=0,0001\left(mol\right)\\ NaOH+HNO_3\rightarrow NaNO_3+H_2O\\ Vì:\dfrac{0,0001}{1}< \dfrac{0,003}{1}\\ \Rightarrow NaOHdư\\ n_{NaOH\left(dư\right)}=0,003-0,0001=0,0029\left(mol\right)\\ \left[OH^-\left(dư\right)\right]=\left[NaOH_{dư}\right]=\dfrac{0,0029}{0,01+0,1}=\dfrac{29}{1100}\left(M\right)\\ \Rightarrow pH=14+log\left[\dfrac{29}{1100}\right]\approx12,421\)
\(n_{H^+}=\left[H^+\right].V=10^{-1}.0,1=0,01\left(mol\right)\)
\(n_{OH^-}=0,1a\left(mol\right)\)
\(n_{OH^-\text{ dư}}=\left[OH^-\right].V=10^{-2}.\left(0,1+0,1\right)=0,002\left(mol\right)\)
Ta có:
\(n_{OH^-}-n_{OH^-\text{ dư}}=n_{H^+}\)
\(\Leftrightarrow0,1a-0,002=0,01\)
\(\Leftrightarrow a=0,12\)
\([H^{+}]=0,1M\\ \Rightarrow n_{H^{+}}=0,1.0,1=0,01(mol)\\ pH=12 \to pOH=14-12=2\\ \Rightarrow [OH^{-}]=0,01\\ \Rightarrow n_{OH^{-}}=0,002(mol)\\ H^{+} +OH^{-} \to H_2O\\ n_{NaOH}=0,01+0,002=0,012(mol)\\ \Rightarrow a=0,12M\)
\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)
\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
Lập tỉ lệ :
\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)
\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)
\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)
\(pH=-log\left(0.01\right)=2\)
\(b.\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.001..........0.002\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)
\(H^++OH^-\rightarrow H_2O\)
Vì dung dịch sau phản ứng pH=12
=> OH- dư
=> \(pOH=14-12=2\)
=> \(\left[OH^-_{dư}\right]=10^{-2}M\)
=> \(n_{OH^-\left(dư\right)}=10^{-2}.0,2=2.10^{-3}\)
Đề thiếu nên không tính được CM của NaOH ban đầu
\(n_{HCl}=0,1.0,002=0,0002\left(mol\right)\\ n_{NaOH}=0,003.0,1=0,0003\left(mol\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ Vì:\dfrac{0,0003}{1}>\dfrac{0,0002}{1}\Rightarrow NaOHdư\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[\dfrac{0,0001}{0,1+0,1}\right]=10,69897\)