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\(a,m_C=10.36\%=3,6\left(kg\right)=3600\left(g\right)\\ n_C=\dfrac{3600}{12}=300\left(mol\right)\\ m_S=10-3,6=6,4\left(kg\right)=6400\left(g\right)\\ n_S=\dfrac{6400}{32}=200\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ S+O_2\rightarrow\left(t^o\right)SO_2\\ n_{O_2\left(tổng\right)}=n_C+n_S=300+200=500\left(mol\right)\\ V_{O_2\left(tổng\right)\left(đktc\right)}=500.22,4=11200\left(l\right)\\ V_{kk}=\dfrac{100}{20}V_{O_2\left(tổng\right)\left(đktc\right)}=5.11200=56000\left(l\right)\\ b,V_{hh\left(CO_2,SO_2\left(đktc\right)\right)}=22,4.\left(n_C+n_S\right)=22,4.\left(300+200\right)=11200\left(l\right)\)
PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{CO}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow n_{O_2\left(1\right)}=0,1\left(mol\right)\\\Sigma n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(2\right)}=0,2\left(mol\right)\) \(\Rightarrow n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow\%V_{H_2}=\dfrac{0,4}{0,4+0,2}\cdot100\%\approx66,67\%\)
\(\Rightarrow\%V_{CO}=33,33\%\)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
a)
2CO + O2 --to--> 2CO2
2H2 + O2 --to--> 2H2O
b) \(n_{H_2O}=\dfrac{12,6}{18}=0,7\left(mol\right)\); \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,6<--0,3<------0,6
2H2 + O2 --to--> 2H2O
0,7<--0,35<------0,7
=> \(\left\{{}\begin{matrix}V_{CO}=0,6.22,4=13,44\left(l\right)\\V_{H_2}=0,7.22,4=15,68\left(l\right)\end{matrix}\right.\)
VO2 = (0,3 + 0,35).22,4 = 14,56 (l)
c) \(M_A=\dfrac{0,6.28+0,7.2}{0,6+0,7}=14\left(g/mol\right)\)
=> \(d_{A/O_2}=\dfrac{14}{32}=0,4375\)
16 nCO2=0,2mol
PTHH: 2CO+O2=>2CO2
0,2<--0,1<---0,2
=> mO2=0,2.32=6,4g
=> khối lượng Oxi phản ứng với H2 là :
9,6-6,4=3,2g
=> nH2O=3,2:32=0,1mol
PTHH: 2H+O2=>H2O
b)
0,2<-0,1<-0,2
=> mH2=2.0,2=0,4g
mCO =0,2.28=5,6g
=> m hh=5,6+0,4=6g
CuO+H2-to--->Cu+H2O
0,6----0,6
nCuO =48/80=0,6 (mol)
==>VH2 =0,6×22,4=13.44(l)
17.
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(m_{H_2SO_4}=200.19,6\%=39,2g\)
\(n_{H_2SO_4}=\dfrac{39,2}{98}=0,4mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,1 < 0,4 ( mol )
0,1 0,1 0,1 0,1 ( mol )
\(V_{H_2}=0,1.22,4=2,24l\)
Chất còn dư là H2SO4
\(m_{H_2SO_4\left(dư\right)}=\left(0,4-0,1\right).98=29,4g\)
\(\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2g\\m_{H_2}=0,1.2=0,2g\end{matrix}\right.\)
\(m_{ddspứ}=5,6+200-0,1.2=205,4g\)
\(\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{205,4}.100=7,4\%\\C\%_{H_2}=\dfrac{0,2}{205,4}.100=0,09\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{205,4}.100=14,31\%\end{matrix}\right.\)
a,
2H2+ O2 (t*)-> 2H2O
CH4+ 2O2 (t*)-> CO2+ 2H2O
M X= 0,325.32= 10,4
nX= 11,2/22,4= 0,5 mol
Gọi x là nH2, y là nCH4
Ta có 2x+16yx+y=10,42x+16yx+y=10,4
<=> 8,4x= 5,6y
<=> xy=5,68,4=23xy=5,68,4=23
Vậy nếu mol H2 là 2x thì mol CH4 là 3x
=> 2x+ 3x= 0,5 <=> x= 0,1
=> nH2= 0,2 mol; nCH4= 0,3 mol
%H2= 0,2.1000,50,2.1000,5= 40%
%CH4= 60%
b,
nO2= 28,8/32= 0,9 mol
Spu đốt H2, tạo ra 0,2 mol H2O; đã dùng 0,1 mol O2
Spu đôts CH4, tạo ra 0,3 mol CO2; 0,6 mol H2O; đã dùng 0,6 mol O2
=> Dư 0,2 mol O2
Sau khi ngưng tụ nước còn lại hh khí gồm 0,3 mol CO2; 0,2 mol O2
%V CO2= 0,3.1000,3+0,20,3.1000,3+0,2= 60%
%V O2= 40%
mCO2= 0,3.44= 13,2g
mO2= 0,2.32= 6,4g
%m CO2= 13,2.1006,4+13,213,2.1006,4+13,2= 67,3%
%m O2= 32,7%
\(a,n_{Al}=\dfrac{19,2\%.27,8}{27}=\dfrac{1112}{5625}\left(mol\right)\\ n_{Fe}=\dfrac{\left(100\%-19,2\%\right).27,8}{56}=\dfrac{14039}{35000}\left(mol\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ n_{O_2\left(tổng\right)}=\dfrac{1112}{5625}.0,75+\dfrac{2}{3}.\dfrac{14039}{35000}\approx0,4156762\left(mol\right)\\ V_{kk\left(đktc\right)}\approx0,4156762.5.22,4\approx46,5557344\left(l\right)\\ b,n_{Al_2O_3}=\dfrac{\dfrac{1112}{5625}}{2}=\dfrac{556}{5625}\left(mol\right)\\ n_{Fe_3O_4}=\dfrac{\dfrac{14039}{35000}}{3}=\dfrac{14039}{105000}\left(mol\right)\\ m_{rắn}=\dfrac{14039}{105000}.232+\dfrac{556}{5625}.102=41,1016381\left(g\right)\)
