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Câu 7: \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right);n_S=\dfrac{0,32}{32}=0,01\left(mol\right)\)
\(Al\rightarrow Al^{3+}+3e\) \(8H^++SO_4^{2-}+6e\rightarrow S+4H_2O\)
\(4H^++SO_4^{2-}+2e\rightarrow SO_2+2H_2O\)
Bảo toàn e : \(n_{SO_2}.2+n_S.6=n_{Al}.3\)
=> \(n_{SO_2}=\dfrac{0,1.3-0,01.6}{2}=0,12\left(mol\right)\)
=> \(V_{SO_2}=2,688\left(l\right)\)
\(n_{H_2SO_4}=\dfrac{0,01.8+0,12.4}{2}=0,28\left(mol\right)\)
Mình bị nhầm chỗ số mol H2SO4 nha
Sửa lại : \(n_{H^+}=4n_{SO_2}=0,6\left(mol\right)\)
Do H2SO4 ---------> 2H+ + SO42-
=> \(n_{H_2SO_4}=\dfrac{1}{2}n_{H^+}=0,3\left(mol\right)\)
a.b.
\(n_{Al}=\dfrac{4,05}{27}=0,15mol\)
\(2Al+6H_2SO_4\left(đ\right)\rightarrow\left(t^o\right)Al_2\left(SO_4\right)_3+3SO_2+6H_2O\)
0,15 0,225 ( mol )
\(V_{SO_2}=0,225.22,4=5,04l\)
c.
\(Ba\left(OH\right)_2+SO_2\rightarrow BaSO_3+H_2O\)
\(Ba\left(OH\right)_2+2SO_2\rightarrow Ba\left(HSO_3\right)_2\)
Gọi \(\left\{{}\begin{matrix}n_{BaSO_3}=x\\n_{Ba\left(HSO_3\right)_2}=y\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}217x+299y=38,7\\x+2y=0,225\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,075\\y=0,075\end{matrix}\right.\)
\(n_{Ba\left(OH\right)_2}=0,075+0,075=0,15mol\)
\(V_{Ba\left(OH\right)_2}=\dfrac{0,15}{1}=0,15l\)
a.b.
nAl=4,0527=0,15molnAl=4,0527=0,15mol
2Al+6H2SO4(đ)→(to)Al2(SO4)3+3SO2+6H2O2Al+6H2SO4(đ)→(to)Al2(SO4)3+3SO2+6H2O
0,15 0,225 ( mol )
VSO2=0,225.22,4=5,04lVSO2=0,225.22,4=5,04l
c.
Ba(OH)2+SO2→BaSO3+H2OBa(OH)2+SO2→BaSO3+H2O
Ba(OH)2+2SO2→Ba(HSO3)2Ba(OH)2+2SO2→Ba(HSO3)2
Gọi {nBaSO3=xnBa(HSO3)2=y{nBaSO3=xnBa(HSO3)2=y
→{217x+299y=38,7x+2y=0,225→{217x+299y=38,7x+2y=0,225 ⇔{x=0,075y=0,075⇔{x=0,075y=0,075
nBa(OH)2=0,075+0,075=0,15molnBa(OH)2=0,075+0,075=0,15mol
VBa(OH)2=0,151=0,15l
