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\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,1 0,2
a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)
1 1 1 1
0,1 0,1
\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)
c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)
1 2 1 1
0,05 0,1
\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
a) PTHH: \(K_2O+H_2O\rightarrow2KOH\)
Ta có: \(n_{KOH}=2n_{K_2O}=2\cdot\dfrac{35,25}{94}=0,75\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,75}{0,75}=1\left(M\right)\)
b) Ta có: \(\left\{{}\begin{matrix}n_{KOH}=0,75\left(mol\right)\\n_{CO_2}=\dfrac{8,4}{22,4}=0,375\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa
PTHH: \(CO_2+2KOH\rightarrow K_2CO_3+H_2O\)
Theo PTHH: \(n_{K_2CO_3}=0,375\left(mol\right)\) \(\Rightarrow m_{K_2CO_3}=0,375\cdot138=51,75\left(g\right)\)
c) PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PTHH: \(n_{H_2SO_4}=0,375\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,375\cdot98}{60\%}=61,25\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,5}\approx40,83\left(ml\right)\)
PTHH: \(K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\)
a+b+c) Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=0,5\left(mol\right)=n_{HCl}\\n_{K_2SO_3}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,25\cdot158=39,5\left(g\right)=a\\m_{KCl}=0,5\cdot74,5=37,25\left(g\right)\\m_{ddHCl}=\dfrac{0,5\cdot36,5}{10,95\%}\approx166,67\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{SO_2}=0,25\cdot64=16\left(g\right)\)
\(\Rightarrow m_{dd}=m_{K_2SO_3}+m_{ddHCl}-m_{SO_2}=190,17\left(g\right)\) \(\Rightarrow C\%_{KCl}=\dfrac{37,25}{190,17}\cdot100\%\approx19,59\%\)
d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Theo PTHH: \(n_{NaOH}=n_{HCl}=0,5\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,5}{0,5}=1\left(l\right)\)
a)
$KOH + SO_2 \to KHSO_3$
Theo PTHH : $n_{KOH} = n_{KHSO_3} = n_{SO_2} = 0,4.0,5 = 0,2(mol)$
$V_{SO_2} = 0,2.22,4 = 4,48(lít)$
$C_{M_{KHSO_3}} = \dfrac{0,2}{0,4} = 0,5M$
b)
$2KOH + SO_2 \to K_2SO_3 + H_2O$
$n_{K_2SO_3} = n_{SO_2} = \dfrac{1}{2}n_{KOH} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
$C_{M_{K_2SO_3}} = \dfrac{0,1}{0,4} = 0,25M$
\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
a,PTHH : \(K_2O+H_2O\rightarrow2KOH\)
\(n_{K_2O}=\frac{m}{M}=\frac{9,4}{39.2+16}=0,1\left(mol\right)\)
- Theo PTHH : \(n_{KOH}=2n_{K_2O}=2.0,1=0,2\left(mol\right)\)
-> \(C_M=\frac{n}{V}=\frac{0,2}{0,5}=0,4\left(M\right)\)
b, - Để phản ứng tạo ra cả hai muối .
<=> \(1< T< 2\)
<=> \(\left\{{}\begin{matrix}\frac{n_{KOH}}{n_{SO_2}}>1\\\frac{n_{KOH}}{n_{SO_2}}< 2\end{matrix}\right.\)
<=> \(\left\{{}\begin{matrix}\frac{0,2}{n_{SO_2}}>1\\\frac{0,2}{n_{SO_2}}< 2\end{matrix}\right.\)
<=> \(0,1< n_{SO_2}< 0,2\left(mol\right)\)
Vậy ....