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200ml = 0,2l
\(n_{Ba\left(OH\right)2}=0,5.0,2=0,1\left(mol\right)\)
Pt : \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O|\)
1 2 1 2
0,1 0,2 0,1
a) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
b) \(n_{BaCl2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
⇒ \(m_{BaCl2}=0,1.208=20,8\left(g\right)\)
c) \(V_{ddspu}=0,2+0,2=0,4\left(l\right)\)
\(C_{M_{BaCl2}}=\dfrac{0,1}{0,4}=0,25\left(M\right)\)
Chúc bạn học tốt
PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Ta có: \(n_{Ba\left(OH\right)_2}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{BaCl_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\\m_{BaCl_2}=0,1\cdot208=20,8\left(g\right)\\C_{M_{BaCl_2}}=\dfrac{0,1}{0,2+0,2}=0,25\left(M\right)\end{matrix}\right.\)
a)
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
Theo PTHH :
$n_{H_2} = n_{Zn} = \dfrac{6,5}{65} = 0,1(mol)$
$V_{H_2} = 0,1.22,4 = 2,24(lít)$
b) $n_{H_2SO_4} = n_{Zn} = 0,1(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,1}{1} = 0,1(lít)$
c) $n_{ZnSO_4} = 0,1(mol) \Rightarrow m_{ZnSO_4} = 0,1.161 = 16,1(gam)$
d) $C_{M_{ZnSO_4}} = \dfrac{0,1}{0,1} = 1M$
nNaOH=0,2mol
a) PTHH: 2NaOH+H2SO4=> Na2SO4+2H2O
0,2=>0,1
=> V H2SO4=0,1:0,5=0,2l=200ml
b) 2NaOH+SO2=>Na2SO3+H2O
2/15=>1/15
NaOH+SO2=>NaHSO3
1/15=>1/15
=> VSO2=2.1/15.22,4=2,98l
\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)
\(n_{SO_2}= \dfrac{7,84}{22,4}=0,35 mol\)
\(n_{Ca(OH)_2}= 0,2 . 1,4=0,28mol\)
Ta có:
\(T=\dfrac{n_{nhóm OH}}{n_{SO_2}}\)\(=\dfrac{2. 0,28}{0,35}= 1,6\)
Có: 1<T<2
Nên Phản ứng tạo hỗn hợp 2 muối trung hòa và axit
\(Ca(OH)_2 + SO_2 \rightarrow CaSO_3 + H_2O\) (1)
\(CaSO_3 + SO_2 + H_2O \rightarrow Ca(HSO_3)_2\) (2)
Theo PTHH (1):
\(n_{SO_2(1)}\)\(n_{CaSO_3} = n_{Ca(OH)_2}= 0,28mol\)
\(\Rightarrow n_{SO_2(2)}=0,35 - 0,28= 0,07 mol\)
Theo PTHH (2):
\(n_{CaSO_3bị hòa tan}\)\(=\)\(n_{Ca(HSO_3)_2}= n_{SO_2(2)}= 0,07 mol\)
Suy ra: \(n_{CaSO_3 sau pư}= 0,28 - 0,07= 0,21 mol\)
\(m_{muối}= m_{CaSO_3} + m_{Ca(HSO_3)_2}= 0,21 .120 + 0,07 . 202= 39,34g\)
b)
\(C_{M Ca(HSO_3)_2}= \dfrac{0,07}{0,2}= 0,35M\)
a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
a)
$KOH + SO_2 \to KHSO_3$
Theo PTHH : $n_{KOH} = n_{KHSO_3} = n_{SO_2} = 0,4.0,5 = 0,2(mol)$
$V_{SO_2} = 0,2.22,4 = 4,48(lít)$
$C_{M_{KHSO_3}} = \dfrac{0,2}{0,4} = 0,5M$
b)
$2KOH + SO_2 \to K_2SO_3 + H_2O$
$n_{K_2SO_3} = n_{SO_2} = \dfrac{1}{2}n_{KOH} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
$C_{M_{K_2SO_3}} = \dfrac{0,1}{0,4} = 0,25M$