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\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ PTHH:2NaOH+H_2SO_4\to Na_2SO_4+2H_2O\\ a,n_{NaOH}=0,4(mol);n_{Na_2SO_4}=0,2(mol)\\ \Rightarrow \begin{cases} m_{Na_2SO_4}=0,2.142=28,4(g)\\ m_{dd_{NaOH}}=\dfrac{0,4.40}{20\%}=80(g) \end{cases}\\ b,2KOH+H_2SO_4\to K_2SO_4+2H_2O\\ \Rightarrow n_{KOH}=0,4(mol)\\ \Rightarrow m_{dd_{KOH}}=\dfrac{0,4.56}{5,6\%}=400(g)\\ \Rightarrow V_{dd_{KOH}}=\dfrac{400}{1,045}=382,78(ml)\)
Bước 1: nH2SO4 = VH2SO4 . CM H2SO4= 0,2 . 1 = 0,2mol
Bước 2:
PTHH: 2NaOH + H2SO4 → Na2SO4 + H2O
2 mol 1 mol
? mol 0,2mol
nNaOH=0,2.21=0,4mol.nNaOH=0,2.21=0,4mol.
m NaOH= n NaOH.MNaOH = 0,4 . (23 + 16 + 1) = 16g
Bước 3: C% = mNaOH : m dd NaOH => mdd NaOH = mNaOH : C% = 16 : 20% = 80g
\(n_{H_3PO_4}=0.2\cdot0.5=0.1\left(mol\right)\)
\(3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\)
\(0.3..............0.1\)
\(m_{dd_{NaOH}}=\dfrac{0.3\cdot40}{40\%}=30\left(g\right)\)
\(V_{dd_{NaOH}}=\dfrac{30}{1.2}=25\left(ml\right)\)
PTHH: \(3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\)
Ta có: \(n_{H_3PO_4}=0,5\cdot0,2=0,1\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddNaOH}=\dfrac{0,3\cdot40}{40\%}=30\left(g\right)\) \(\Rightarrow V_{ddNaOH}=\dfrac{30}{1,2}=25\left(ml\right)\)
FeO+H2SO4------->FeSO4+ H2
nFeO=7,2/72=0,1 (mol)
---->nH2SO4=0,1 mol
----->mH2SO4=0,1.98=9,8(g)
---->mdung dich H2SO4=(9,8.100)/49=20(g)
--->Vdung dịch H2SO4=20/1,35=14,8(l)
2NaOH+H2SO4------>Na2SO4+2H2O
nNaOH=2.0,1=0,2(mol)
---->Vnaoh=0,2/1=0,2l
a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
Lập tỉ lệ : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)=> Sau phản ứng NaOH dư
\(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
Dung dịch nước lọc gồm NaCl (0,4_mol); NaOH dư ( 0,1 mol)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\)
\(a=m_{CuO}=0,2.80=16\left(g\right)\)
b) \(m_{NaCl}=0,4.58,5=23,4\left(g\right);m_{NaOH}=0,1.40=4\left(g\right)\)
mddNaOH=200*1,2=240g
C%ddNaOH=\(\frac{3,5}{240}\)*100%=1,46%