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PTHH: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
a) Ta có: \(n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{\dfrac{1}{15}\cdot56}{13,6}\cdot100\%\approx27,45\%\) \(\Rightarrow\%m_{CuO}=72,55\%\)
b) Ta có: \(m_{CuO}=13,6-\dfrac{1}{15}\cdot56\approx9,9\left(g\right)\) \(\Rightarrow n_{CuO}=n_{H_2SO_4}=\dfrac{9,9}{80}=0,12375\left(mol\right)\)
*Làm gì có H2SO4 loãng đâu nhỉ ??
a, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,2<---------------------------0,2
\(\rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Cu}=16-11,2=4,8\left(g\right)\end{matrix}\right.\)
b, \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{32}{16}.0,2=0,4\left(mol\right)\\n_{Cu}=\dfrac{4,8}{64}.\dfrac{32}{16}=0,15\left(mol\right)\end{matrix}\right.\)
PTHH:
Cu + 2H2SO4 (đặc, nóng) ---> CuSO4 + SO2 + 2H2O
0,15--------------------------------------------->0,15
2Fe + 6H2SO4 (đặc, nóng) ---> Fe2(SO4)3 + 3SO2 + 6H2O
0,4------------------------------------------------------>0,6
=> VSO2 = (0,6 + 0,15).22,4 = 16,8 (l)
c, \(n_{NaOH}=0,375.2=0,75\left(mol\right)\)
\(T=\dfrac{0,75}{0,6+0,15}=1\) => tạo duy nhất muối axit (NaHSO3)
PTHH: NaOH + SO2 ---> NaHSO3
0,75----------------->0,75
=> mmuối = 0,75.104 = 78 (g)
\(a)n_{Mg} = a(mol) ; n_{Fe} = b(mol) \Rightarrow 24a + 56b =2 0(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = a + b =\dfrac{11,2}{22,4} = 0,5(2)\\ (1)(2) \Rightarrow a = b = 0,25\\ \%m_{Mg} = \dfrac{0,25.24}{20}.100\% = 30\%\\ \%m_{Fe} = 100\%-30\% = 70\%\\ b) \\Mg^0 \to Mg^{2+} + 2e;Fe^0 \to Fe^{3+} + 3e\\ S^{+6} \to S^{+4} + 2e\\ 2n_{Mg} + 3n_{Fe} = 2n_{SO_2}\)
\(n_{SO_2} = \dfrac{0,25.2 + 0,25.3}{2} = 0,625(mol)\\ V_{SO_2} = 0,625.22,4 = 14(lít)\)
Bài 1:
Ta có: \(n_{Fe}=0,1\left(mol\right)\)
PT: \(Fe+4HNO_3\underrightarrow{t^o}Fe\left(NO_3\right)_3+NO+2H_2O\)
___0,1_____0,4_____0,1_______0,1 (mol)
\(\Rightarrow m_{HNO_3}=0,4.63=25,2\left(g\right)\)
\(\Rightarrow m_{ddHNO_3}=\dfrac{25,2}{6,3\%}=400\left(g\right)\)
Ta có: m dd sau pư = mFe + m dd HNO3 - mNO = 5,6 + 400 - 0,1.30 = 402,6 (g)
\(\Rightarrow C\%_{Fe\left(NO_3\right)_3}=\dfrac{0,1.242}{402,6}.100\%\approx6,01\%\)
Bạn tham khảo nhé!
a/nH2= 0,1(mol)
Fe + H2SO4 -> FeSO4 + H2
0,1_________________0,1(mol)
=> mFe=0,1.56=5,6(g)
=> %mFe= (5,6/12).100\(\approx\) 46,667%
=> %mCu \(\approx\) 100% - 46,667% \(\approx\) 53,333%
b) mCu= 12-5,6=6,4(g) -> nCu= 0,1(mol)
Cu + 2 H2SO4(đ) -to-> CuSO4 + SO2 + 2 H2O
0,1___0,2__________________0,1(mol)
V=V(SO2,đktc)=0,1.22,4=2,24(l)
mH2SO4(p.ứ)=0,2.98=19,6(g)
=> mH2SO4(bđ)= 19,6 x 100/90 \(\approx21,778\left(g\right)\)
=> mddH2SO4 \(\approx\) (21,778 x 100)/98\(\approx22,222\left(g\right)\)