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Bài 1:
PTHH: \(C_2H_5OH+O_2\xrightarrow[]{mengiấm}CH_3COOH+H_2O\)
Ta có: \(n_{C_2H_5OH}=\dfrac{115\cdot0,8}{46}=2\left(mol\right)=n_{CH_3COOH\left(lýthuyết\right)}\)
\(\Rightarrow m_{CH_3COOH\left(thực\right)}=2\cdot60\cdot90\%=108\left(g\right)\)
Bài 2:
PTHH: \(C_2H_5OH+CH_3COOH\xrightarrow[H_2SO_4\left(đ\right)]{t^o}CH_3COOC_2H_5+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{60}{60}=1\left(mol\right)\\n_{C_2H_5OH}=\dfrac{92}{46}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Rượu còn dư, Axit p/ứ hết
\(\Rightarrow n_{CH_3COOC_2H_5\left(lýthuyết\right)}=1\left(mol\right)\) \(\Rightarrow m_{CH_3COOC_2H_5\left(thực\right)}=1\cdot88\cdot80\%=70,4\left(g\right)\)
a, \(n_{CO_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{CH_3COOH}=2n_{CO_2}=0,05\left(mol\right)\)
\(\Rightarrow C\%_{CH_3COOH}=\dfrac{0,05.60}{100}.100\%=3\%\)
b, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,025\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,025.106=2,65\left(g\right)\)
\(n_{CH_3COONa}=2n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
c, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,05\left(mol\right)\)
Mà: H = 80%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,05}{80\%}=0,0625\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,0625.46=2,875\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{2,875}{0,8}=3,59375\left(ml\right)\)
\(\Rightarrow V_{C_2H_5OH\left(10^o\right)}=\dfrac{3,59375}{10}.100=35,9375\left(ml\right)\)
