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a, \(n_{CO_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{CH_3COOH}=2n_{CO_2}=0,05\left(mol\right)\)
\(\Rightarrow C\%_{CH_3COOH}=\dfrac{0,05.60}{100}.100\%=3\%\)
b, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,025\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,025.106=2,65\left(g\right)\)
\(n_{CH_3COONa}=2n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
c, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,05\left(mol\right)\)
Mà: H = 80%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,05}{80\%}=0,0625\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,0625.46=2,875\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{2,875}{0,8}=3,59375\left(ml\right)\)
\(\Rightarrow V_{C_2H_5OH\left(10^o\right)}=\dfrac{3,59375}{10}.100=35,9375\left(ml\right)\)
Bài 1:
PTHH: \(C_2H_5OH+O_2\xrightarrow[]{mengiấm}CH_3COOH+H_2O\)
Ta có: \(n_{C_2H_5OH}=\dfrac{115\cdot0,8}{46}=2\left(mol\right)=n_{CH_3COOH\left(lýthuyết\right)}\)
\(\Rightarrow m_{CH_3COOH\left(thực\right)}=2\cdot60\cdot90\%=108\left(g\right)\)
Bài 2:
PTHH: \(C_2H_5OH+CH_3COOH\xrightarrow[H_2SO_4\left(đ\right)]{t^o}CH_3COOC_2H_5+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{60}{60}=1\left(mol\right)\\n_{C_2H_5OH}=\dfrac{92}{46}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Rượu còn dư, Axit p/ứ hết
\(\Rightarrow n_{CH_3COOC_2H_5\left(lýthuyết\right)}=1\left(mol\right)\) \(\Rightarrow m_{CH_3COOC_2H_5\left(thực\right)}=1\cdot88\cdot80\%=70,4\left(g\right)\)
\(n_{CO2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Pt : \(C_6H_{12}O_6\xrightarrow[30-35^oC]{Menrượu}2C_2H_5OH+2CO_2\)
0,5 0,5
a) \(m_{C2H5OH}=0,5.46=23\left(g\right)\)
b) Pt : \(C_2H_5OH+O_2\xrightarrow[]{Mengiấm}CH_3COOH+H_2O\)
0,5 0,5
\(m_{CH3COOH\left(lt\right)}=0,5.60=30\left(g\right)\)
⇒ \(m_{CH3COOH\left(tt\right)}=30.80\%=24\left(g\right)\)
Chúc bạn học tốt
\(C_6H_{12}O_6\underrightarrow{t^o}2C_2H_5OH+2CO_2\uparrow\)(xt : men rượu )
0,5 0,5
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(m_{C_2H_5OH}=0,5.46=23\left(g\right)\)
\(C_2H_5OH+O_2\underrightarrow{t^o}CH_3COOH+H_2O\) (men giấm )
0,5 0,5
\(m_{CH_3COOH}=0,5.60=30\left(g\right)\)
\(m_{CH_3COOHtt}=30.80\%=24\left(g\right)\)
a) C2H5OH + O2 --men giấm--> CH3COOH + H2O
b) \(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: C2H5OH + O2 --men giấm--> CH3COOH + H2O
0,3<----0,3------------------>0,3
=> \(m_{C_2H_5OH}=0,3.46=13,8\left(g\right)\)
=> \(V_{C_2H_5OH}=\dfrac{13,8}{0,8}=17,25\left(ml\right)\)
=> \(Độ.rượu=\dfrac{17,25}{150}.100=11,5^o\)
c) \(m_{CH_3COOH}=0,3.60=18\left(g\right)\)
Đổi 10kg = 10000g
Ta có: \(n_{CH_3COOH\left(LT\right)}=\dfrac{10000.5\%}{92\%}=\dfrac{12500}{23}\left(mol\right)\)
PTHH:
\(C_2H_5OH+O_2\xrightarrow[]{\text{men giấm}}CH_3COOH+H_2O\)
\(\dfrac{12500}{23}\)<---------------------\(\dfrac{12500}{23}\)
\(\Rightarrow m_{C_2H_5OH}=\dfrac{12500}{23}.46=25000\left(g\right)=25\left(kg\right)\)
Bạn xem lại xem đề cho pư với NaHCO2 hay Na2CO3 nhé.