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Theo bài ra, ta có: \(m_{Ag}=5,6\left(g\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
a) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) \(\Rightarrow n_{Al}=\dfrac{1}{15}\left(mol\right)\) \(\Rightarrow m_{Al}=\dfrac{1}{15}\cdot27=1,8\left(g\right)\)
\(\Rightarrow\%m_{Al}=\dfrac{1,8}{1,8+5,6}\cdot100\%\approx24,32\%\) \(\Rightarrow\%m_{Ag}=75,68\%\)
b) Theo PTHH: \(n_{H_2SO_4}=n_{H_2}=0,1mol\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
c) PTHH: \(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4\downarrow+2H_2O\)
Theo PTHH: \(n_{Ba\left(OH\right)_2}=n_{H_2SO_4}=0,1mol\)
\(\Rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{0,1}{0,2}=0,5\left(l\right)=500\left(ml\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Zn+H_2SO_4\to ZnSO_4+H_2\\ b,n_{Zn}=0,1(mol)\Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{10,5}.100\%=61,9\%\\ \Rightarrow \%_{Cu}=100\%-61,9\%=38,1\%\\ c,n_{H_2SO_4}=0,1(mol)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
0.1 0.1
nH2= 2.24: 22.4=0.1 mol
mZn= 0.1x65=6.5 g
mCu=10.5-6,5=4 g
%Zn=6.5:10.5x100%=61.9%
%Cu=4:10.5x100%=38.1%
a) Đặt: nZn=x(mol); nFe= y(mol) (x,y: nguyên, dương)
Zn + H2SO4 -> ZnSO4 + H2
x_______x_______x________x
Fe + H2SO4 -> FeSO4 + H2
y____y_________y___y(mol)
b) m(rắn)=mCu=3(g)
=> m(Zn, Fe)= 21,6 - 3= 18,6(g)
Ta có hpt:
\(\left\{{}\begin{matrix}65x+56y=18,6\\22,4x+22,4y=6,72\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
=> Zn= 65.0,2=13(g)
=>%mZn= (13/21,6).100=60,185%
%mCu=(3/21,6).100=13,889%
=>%mFe=25,926%
c) nH2SO4=x+y=0,3(mol) =>mH2SO4=29,4(g)
=> mddH2SO4= (29,4.100)/25=117,6(g)
a) PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1\cdot65}{6,5+2,16}\cdot100\%\approx75,06\%\\\%m_{Ag}=24,94\%\end{matrix}\right.\)
c) Theo PTHH: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
d) PTHH: \(2Ag+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}Ag_2SO_4+SO_2\uparrow+2H_2O\)
Ta có: \(n_{SO_2}=\dfrac{1}{2}n_{Ag}=\dfrac{1}{2}\cdot\dfrac{2,16}{108}=0,01\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,01\cdot22,4=0,224\left(l\right)\)