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a) Fe + 2HCl --> FeCl2 + H2
FeO + 2HCl --> FeCl2 + H2O
b) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
______0,5<-1<------0,5<---0,5
=> mFe = 0,5.56 = 28 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{28}{100}.100\%=28\%\\\%FeO=100\%-28\%=72\%\end{matrix}\right.\)
c) \(n_{FeO}=\dfrac{72}{72}=1\left(mol\right)\)
PTHH: FeO + 2HCl --> FeCl2 + H2O
______1---->2
=> mHCl = (1+2).36,5 = 109,5 (g)
=> \(m_{ddHCl}=\dfrac{109,5.100}{30}=365\left(g\right)\)
=> \(V_{ddHCl}=\dfrac{365}{1,15}=317,39\left(ml\right)\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO +2 HCl \to FeCl_2 + H_2O$
b)
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$\%m_{Fe} = \dfrac{0,2.56}{20}.100\% = 56\%$
$\%m_{FeO} = 100\% - 56\% = 44\%$
c) $n_{FeO} = \dfrac{11}{90}(mol)$
$n_{HCl} = 2n_{Fe} + 2n_{FeO} = \dfrac{29}{45}(mol)$
$m_{dd\ HCl} = \dfrac{ \dfrac{29}{45}.36,5}{7,3\%} = 322,22(gam)$
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
nAl= 0,5(mol)
a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2
nHCl= 6/2 . 0,5= 1,5(mol)
=>mHCl= 1,5.36,5=54,75(mol)
=> mddHCl= (54,75.100)/18,25=300(g)
b) nH2= 3/2. 0,5=0,75(mol)
=>V(H2,đktc)=0,75.22,4=16,8(l)
c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)
mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)
=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)
a, Ta có: \(n_{CO}=\dfrac{6,72}{22,4}=0,3\left(mol\right)=n_{CO_2}\)
Theo ĐLBT KL, có: mhh + mCO = mFe + mCO2
⇒ mFe = 18,2 + 0,3.28 - 0,3.44 = 13,4 (g)
b, Giả sử: \(\left\{{}\begin{matrix}n_{Ca}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\)
⇒ x + y = 0,2 (1)
PT: \(Ca+2HCl\rightarrow CaCl_2+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(CaCl_2+Na_2CO_3\rightarrow CaCO_{3\downarrow}+2NaCl\)
\(MgCl_2+Na_2CO_3\rightarrow MgCO_{3\downarrow}+2NaCl\)
Theo PT: \(\left\{{}\begin{matrix}n_{CaCO_3}=n_{Ca}=x\left(mol\right)\\n_{MgCO_3}=n_{Mg}=y\left(mol\right)\end{matrix}\right.\)
⇒ 100x + 84y = 18,4 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
Theo PT: \(\left\{{}\begin{matrix}n_{CaCl_2}=n_{Ca}=0,1\left(mol\right)\\n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ a = mCaCl2 + mMgCl2 = 0,1.111 + 0,1.95 = 20,6 (g)
Bạn tham khảo nhé!
Bài 1:
Ta có: \(n_{H_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\)
Bảo toàn Hidro: \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\) \(\Rightarrow m_{HCl\left(p.ứ\right)}=0,4\cdot36,5=14,6\left(g\right)\)
Bảo toàn khối lượng: \(m_{muối}=m_{KL}+m_{HCl\left(p.ứ\right)}-m_{H_2}=24,7\left(g\right)\)
Bài 2:
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)
\(\Rightarrow\%m_{Fe}=\dfrac{0,1\cdot56}{12,8}\cdot100\%=43,75\%\) \(\Rightarrow\%m_{FeO}=56,25\%\)