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Bài 1:
\(a.n_{NaOH\left(tổng\right)}=0,05.1+0,2.0,2=0,09\left(mol\right)\\ V_{ddNaOH\left(tổng\right)}=50+200=250\left(ml\right)=0,25\left(l\right)\\ C_{MddNaOH\left(cuối\right)}=\dfrac{0,09}{0,25}=0,36\left(M\right)\\ b.n_{HCl}=0,5.0,02=0,01\left(mol\right)\\ n_{H_2SO_4}=0,08.0,2=0,016\left(mol\right)\\ V_{ddsau}=20+80=100\left(ml\right)=0,1\left(l\right)\\ C_{MddH_2SO_4}=\dfrac{0,016}{0,1}=0,16\left(M\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\)
Bài 2:
\(a.m_{H_2SO_4}=29,4.10\%=2,94\left(g\right)\\ b.n_{H_2SO_4}=\dfrac{2,94}{98}=0,03\left(mol\right)\\ n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,03}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(dư\right)}=0,03-0,01=0,02\left(mol\right)\\ m_{H_2SO_4\left(dư\right)}=0,02.98=1,96\left(g\right)\\ n_{H_2}=n_{Fe}=0,01\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)
nNa = 6.9 : 23 = 0.3 mol
4Na + O2 ->2 Na2O
mol : 0.3 -> 0.15
Na2O + H2O -> 2NaOH
mol : 0.15 -> 0.3
mdd = 0.15 x 62 + 140.7 = 150g
C% NaOH = 0.3x40: 150 x 100% = 8%
\(n_{P_2O_5}=\dfrac{99,4}{142}=0,7\left(mol\right)\)
\(P_2O_5+3H_2O\rightarrow2H_3PO_4\)
0,7 2,1 1,4
a, \(m_{H_3PO_4}=1,4.98=137,2\left(g\right)\)
\(m_{ddH_3PO_4}=99,4+500=599,4\left(g\right)\)
Kl nước trong dd A :
\(m_{H_2O}=599,4-137,2=462,2\left(g\right)\)
\(b,C\%_{H_3PO_4}=\dfrac{137,2}{599,4}.100\%\approx22,89\%\)
\(c,C_M=\dfrac{n}{V}=\dfrac{1,4}{0,5}=2,8M\)
a)Gọi C% của dd sau khi trộn là x (%)
Ta có sơ đồ đường chéo:
50g NaOH 8% ........................... 20-x
................ x (%)............
450g NaOH 20%........................... x-8
=> \(\dfrac{50}{250}=\dfrac{20-x}{x-8}\)<=> x = 18,8 %
b) CM = \(\dfrac{18,8.1,1}{40}\)= 0,517 (mol/lít)
mNaOH = \(\dfrac{\left(45+450\right).18,8}{100}\)100 = 94 (g) => nNaOH = \(\dfrac{94}{40}\) = 2,35(mol)
=> Vdd = \(\dfrac{2,35}{0,517}\)≈ 4,55 (l)
a)
C% CuSO4 = 16/(16 + 184) .100% = 8%
b)
n NaOH = 20/40 = 0,5(mol)
CM NaOH = 0,5/4 = 0,125M
\(n_{Na_2CO_3\left(tổng\right)}=\dfrac{14,3}{286}.106+250.5,3\%=18,55\left(g\right)\\ C\%_{ddNa_2CO_3}=\dfrac{18,55}{14,3+250}.100\approx7,019\%\)
2NaOH+H2SO4->Na2SO4+2H2O
0,05-----0,025---------0,025-----0,05
m NaOH=2 g
=>n NaOH=0,05mol
->m H2SO4=0,025.98=2,45g
=>C%=\(\dfrac{2,45}{50}100\)=4,9%
b)C%Na2SO4=\(\dfrac{0,025.142}{20+50+0,9}100\)=5%