Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{BaCl_2}=0.2\cdot0.5=0.1\left(mol\right)\)
\(BaCl_2+K_2SO_4\rightarrow BaSO_4+2KCl\)
\(0.1.............0.1.........................0.2\)
\(V_{dd_{K_2SO_4}}=\dfrac{0.1}{1}=0.1\left(l\right)\)
\(V_{dd}=0.2+0.1=0.3\left(l\right)\)
\(C_{M_{KCl}}=\dfrac{0.2}{0.3}=0.67\left(M\right)\)
Đổi 200ml = 0,2 lít
Ta có: \(n_{BaCl_2}=0,5.0,2=0,1\left(mol\right)\)
a. PTHH: \(BaCl_2+K_2SO_4--->BaSO_4\downarrow+2KCl\)
Theo PT: \(n_{K_2SO_4}=n_{BaCl_2}=0,1\left(mol\right)\)
\(\Rightarrow V_{dd_{K_2SO_4}}=\dfrac{0,1}{1}=0,1\left(lít\right)\)
b. Theo PT: \(n_{KCl}=2.n_{BaCl_2}=2.0,1=0,2\left(mol\right)\)
Ta có: \(V_{dd_{KCl}}=V_{dd_{BaCl_2}}=0,1\left(lít\right)\)
\(\Rightarrow C_{M_{KCl}}=\dfrac{0,2}{0,1}=2M\)
nH2SO4 = nBaSO4 = 0,1
-> y = 0,2 (mol/l)
nAl2O3 = 0,01
TH1: Axit dư:
H2SO4 + 2NaOH —> Na2SO4 + 2H2O
0,25x 0,5x
3H2SO4 + Al2O3 —> Al2(SO4)3 + 3H2O
0,03 0,01
-> nH2SO4 = 0,25x + 0,03 = 0,1
-> x = 0,28 (mol/l)
TH2: NaOH dư:
H2SO4 + 2NaOH —> Na2SO4 + 2H2O
0,1 0,2
Al2O3 + 2NaOH —> 2NaAlO2 + H2O
0,01 0,02
-> nNaOH tổng = 0,5x = 0,22
-> x = 0,44 (mol/l)
Vậy \(\left[{}\begin{matrix}x=0,28\\x=0,44\end{matrix}\right.\)(mol/l)
y = 0,2 (mol/l)
a) \(n_{K2SO4}=\dfrac{17,4}{174}=0,1\left(mol\right)\)
PTHH : \(K_2SO_4+BaCl_2-->BaSO_4\downarrow+2KCl\)
Theo PTHH :nBaSO4 = nK2SO4 = 0,1 (mol)
=> mBaSO4 = 0,1. 233 = 23,3 (g)
b) Theo PTHH :
nKCl = 2nK2SO4 = 0,2 (mol)
nBaCl2 = nK2SO4 = 0,1 (mol)
=> mBaCl2 = 0,1.208 = 20,8 (g)
=> m(ddBaCl2) = 20,8 : 10.100 = 208 (g)
Áp dụng định luật bảo toàn khối lượng :
mK2SO4 + m(ddBaCl2) = mBaSO4 + m(ddKCl)
=> 17,4 + 208 = 23,3 + m(ddKCl)
=> m(ddKCl) = 202,1 (g)
=> \(C\%KCl=\dfrac{0,2.74,5}{202,1}\cdot100\%\approx7,37\%\)
\(\begin{array}{l} a,\\ n_{K_2SO_4}=\dfrac{17,4}{174}=0,1\ (mol)\\ PTHH:K_2SO_4+BaCl_2\to BaSO_4\downarrow+2KCl\\ Theo\ pt:\ n_{BaSO_4}=n_{K_2SO_4}=0,1\ (mol)\\ \Rightarrow m_{BaSO_4}=0,1\times 233=23,3\ (g)\\ b,\\ Theo\ pt:\ n_{BaCl_2}=n_{K_2SO_4}=0,1\ (mol)\\ \Rightarrow m_{\text{dd BaCl_2}}=\dfrac{0,1\times 208}{10\%}=208\ (g)\\ m_{\text{dd spư}}=m_{K_2SO_4}+m_{\text{dd BaCl_2}}-m_{BaSO_4}\\ \Rightarrow m_{\text{dd spư}}=17,4+208-23,3=202,1\ (g)\\ Theo\ pt:\ n_{KCl}=2n_{K_2SO_4}=0,2\ (mol)\\ \Rightarrow C\%_{\text{dd spư}}=C\%_{KCl}=\dfrac{0,2\times 74,5}{202,1}\times 100\%=7,37\%\end{array}\)
\(m_{H_2SO_4}=\dfrac{19,6\cdot20\%}{100\%}=3,92\left(g\right)\\ \Rightarrow n_{H_2SO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\\ PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \Rightarrow n_{H_2SO_4}=n_{BaCl_2}=n_{BaSO_4}=0,04\left(mol\right)\\ \Rightarrow m_{CT_{BaCl_2}}=0,04\cdot208=8,32\left(g\right)\\ \Rightarrow m_{dd_{BaCl_2}}=\dfrac{8,32\cdot100\%}{12\%}\approx69,3\left(g\right)\\ m_{kết.tủa}=m_{BaSO_4}=0,04\cdot233=9,32\left(g\right)\)
\(n_{K_2SO_4}=1\cdot0,2=0,2\left(mol\right)\\ n_{BaCl_2}=2\cdot0,15=0,3\left(mol\right)\\ PTHH:K_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2KCl\\ \text{Vì }\dfrac{n_{K_2SO_4}}{1}< \dfrac{n_{BaCl_2}}{1}\text{ nên sau p/ứ }BaCl_2\text{ dư}\\ \Rightarrow n_{BaSO_4}=n_{K_2SO_4}=0,2\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{BaSO_4}=0,2\cdot233=46,6\left(g\right)\)
Na2SO4 + BaCl2 →2NaCl + BaSO4
nNa2SO4=0,05.0,1=0,005(mol)
nBaCl2=0,1.0,1=0,01(mol)
Vì 0,005<0,01 nên BaCl2 dư 0,005(mol)
Theo PTHH ta có;
nNa2SO4=nBaSO4=0,005(mol)
2nNa2SO4=nNaCl=0,01(mol)
mBaSO4=0,005.233=1,165(g)
CM dd BaCl2=\(\dfrac{0,005}{0,15}=\dfrac{1}{30}\)M
CM dd NaCl=\(\dfrac{0,01}{0,15}=115\)M
a) \(\left\{{}\begin{matrix}n_{CuSO_4}=0,3.1=0,3\left(mol\right)\\n_{BaCl_2}=0,1.2=0,2\left(mol\right)\end{matrix}\right.\)
PTHH: \(CuSO_4+BaCl_2\rightarrow BaSO_4\downarrow+CuCl_2\)
Ban đầu: 0,3 0,2
Sau pư: 0,1 0 0,2 0,2
=> \(m_{kt}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\)
b) \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,1-------->0,2
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+2NaCl\)
0,2------>0,4
=> \(m_{ddNaOH}=\dfrac{\left(0,2+0,4\right).40}{15\%}=160\left(g\right)\)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
$n_{BaCl_2} = n_{K_2SO_4} = 0,2.1 = 0,2(mol)$
$V_{dd\ BaCl_2} = \dfrac{0,2}{1,5} = 0,1333(lít)$