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\(\%m_{Ca}=\dfrac{40}{164}.100=24,39\left(\%\right)\\ \%m_N=\dfrac{28}{164}.100=17,07\left(\%\right)\\ \%m_O=\dfrac{48.2}{164}.100=58,54\left(\%\right)\)
\(M_{KMnO_4}=158(g/mol)\\ \%_{K}=\dfrac{39}{158}.100\%=24,68\%\\ \%_{Mn}=\dfrac{55}{158}.100\%=34,81\%\\ \%_O=100\%-24,68\%-34,81\%=40,51\%\)
\(CaCO_3\\ \%m_{Ca}=\dfrac{40}{40+12+3.16}.100=40\%\\ \%m_C=\dfrac{12}{40+12+16.3}.100=12\%\\ \Rightarrow\%m_O=100\%-\left(40\%+12\%\right)=48\%\\ H_2SO_4\\ \%m_H=\dfrac{2.1}{2.1+32+4.16}.100\approx2,041\%\\ \%m_S=\dfrac{32}{2.1+32+4.16}.100\approx32,653\%\\ \%m_O=\dfrac{4.16}{2.1+32+4.16}.100\approx65,306\%\\ Fe_2O_3\\ \%m_{Fe}=\dfrac{56.2}{56.2+16.3}.100=70\%\\ \Rightarrow\%m_O=100\%-70\%=30\%\)
CaCO3
\(\%M_{\dfrac{Ca}{CaCO_3}}=\dfrac{40}{100}.100\%=40\%\)
\(\%M_{\dfrac{C}{CaCO_3}}=\dfrac{12}{100}.100\%=12\%\)
\(\%M_{\dfrac{O}{CaCO_3}}=100\%-\left(40\%+12\%\right)=48\%\)
H2SO4
\(\%M_{\dfrac{H_2}{H_2SO_4}}=\dfrac{2}{98}.100\%=2,04\%\)
\(\%M_{\dfrac{S}{H_2SO_4}}=\dfrac{32}{98}.100\%=32,65\%\)
\(\%M_{\dfrac{O}{H_2SO_4}}=100\%-\left(2,04\%+32,65\%\right)=65,31\%\)
Fe2O3
\(\%M_{\dfrac{Fe}{Fe_2O_3}}=\dfrac{112}{160}.100\%=70\%\)
\(\%M_{\dfrac{O}{Fe_2O_3}}=100\%-70\%=30\%\)
\(CaO:\%^MCa=\dfrac{40}{40+16}\cdot100\%=71,43\%\\ \%^MO=100\%-71,43\%=28,57\%\)
\(MgCO_3:\%^MMg=\dfrac{24}{24+12+16\cdot3}\cdot100\%=28,57\%\\ \%^MC=\dfrac{12}{24+12+16\cdot3}\cdot100\%=14,29\%\\ \%^MO=100\%-28,57\%-14,29\%=57,14\%\)
\(NaOH:\%^MNa=\dfrac{23}{23+16+1}\cdot100\%=57,5\%\\ \%^MO=\dfrac{16}{23+16+1}\cdot100\%=40\%\\ \%^MH=100\%-57,5\%-40\%=2,5\%\)
b,
Ta có: dX/O2=1,375
=>Mx =1,375.32
=44(g/mol)
Ta lại có:
12.x/27,27=16.y/72,73=44/100
=>x=27,27.44/12.100=1
=> y=72,73.44/16.100=2
Vậy CTHH: CO2
\(\%m_S=\dfrac{32}{80}.100\%=40\%\)
\(\%m_O=\dfrac{3.16}{80}.100\%=60\%\)
\(\%_{Mg}=\dfrac{24}{146}.100\%=16,4\%\)
\(\%_H=\dfrac{1.2}{146}.100\%=1,4\%\)
\(\%_C=\dfrac{12.2}{146}.100\%=16,4\%\)
\(\%_O=100\%-16,4\%-1,4\%-16,4\%=65,8\%\)