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Câu 1:
Theo bài:
\(2p_X+n_X+2\left(2p_Y+n_Y\right)=69\)
\(\Leftrightarrow2\left(p_X+2p_Y\right)+\left(n_X+2_Y\right)=69\left(1\right)\)
\(2\left(p_X+2p_Y\right)-\left(n_X+2n_Y\right)=23\left(2\right)\)
\(\left(1\right)+\left(2\right)\Rightarrow\left\{{}\begin{matrix}p_X+2p_Y=23\left(3\right)\\n_X+2n_Y=23\end{matrix}\right.\)
Mà \(-2p_X+2p_Y=2\left(4\right)\)
\(\left(3\right)+\left(4\right)\Rightarrow\left\{{}\begin{matrix}p_X=7\left(N\right)\\n_Y=8\left(O\right)\end{matrix}\right.\)
Vậy khí A là NO2
a) 2KClO3 --to--> 2KCl + 3O2
b) \(n_{KClO_3}=\dfrac{36,75}{122,5}=0,3\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,3----------------->0,45
=> V = 0,45.22,4 = 10,08 (l)
nKClO3 = 36,75 : 122,5 = 0,3 (mol)
pthh : 2KClO3 -t--> 2KCl + 3O2
0,3----------------------->0,45 (mol)
=> V= VO2 = 0,45 . 22,4 = 10,08 (L)
Bài 1:
a) PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+2H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}m_{Fe_2O_3}=20\cdot80\%=16\left(g\right)\\m_{CuO}=20-16=4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=0,35\left(mol\right)\) \(\Rightarrow V_{H_2}=0,35\cdot22,4=7,84\left(l\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)\\n_{Cu}=n_{CuO}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hhB}=m_{Fe}+m_{Cu}=0,2\cdot56+0,05\cdot64=14,4\left(g\right)\)
Bài 2:
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a) Vì khối lượng Cu bằng \(\dfrac{6}{5}\) khối lượng Fe
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=\dfrac{26,4}{6+5}\cdot6=14,4\left(g\right)\\m_{Fe}=26,4-14,4=12\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=\dfrac{14,4}{64}=0,225\left(mol\right)\\n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{3}{2}n_{Fe}+n_{Cu}=\dfrac{9}{28}+0,225=\dfrac{153}{280}\left(mol\right)\) \(\Rightarrow V_{H_2}=\dfrac{153}{280}\cdot22,4=12,24\left(l\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{28}\left(mol\right)\\n_{CuO}=n_{Cu}=0,225\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=\dfrac{3}{28}\cdot160\approx17,14\left(g\right)\\m_{CuO}=0,225\cdot80=18\left(g\right)\end{matrix}\right.\) \(\Rightarrow m_{hh}=35,14\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{17,14}{35,14}\cdot100\%\approx48,78\%\\\%m_{CuO}=51,22\%\end{matrix}\right.\)
a)\(n_{CuO}=\dfrac{16}{80}=0,2mol\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
b)\(n_{Na}=\dfrac{4,6}{23}=0,2mol\)
\(n_{H_2O}=\dfrac{100}{18}=\dfrac{50}{9}mol\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(0,2\) \(\dfrac{50}{9}\) 0 0
\(0,2\) 0,2 0,2 0,1
0 \(5,35\) 0,2 0,1
\(V_{H_2}=0,1\cdot22,4=2,24l\)
\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{H_2} = n_{CuO} = \dfrac{16}{80} = 0,2(mol)\\ \Rightarrow V_{H_2} = 0,2.22,4 = 4,48(lít)\)
\(1) Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O \text{Theo PTHH }\\ n_{H_2O} = n_{H_2} = \dfrac{20,16}{22,4}=0,9(mol)\\ \text{Bảo toàn khối lượng : }\\ a = m_{hh} + m_{H_2} - m_{H_2O} = 65,4 + 0,9.2 - 0,9.18 = 51(gam)\)
2)
\(n_{Mg} = a ; n_{Al} = b ; n_{Fe} = c\\ \Rightarrow 24a + 27b + 56c = 18,6(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{14,56}{22,4}=0,65(2)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{O_2} = \dfrac{7,84}{22,4} = 0,35\)
Ta có :
\(\dfrac{a + b + c}{0,5a + 0,75b + \dfrac{2}{3}c} = \dfrac{0,55}{0,35}(3)\\ (1)(2)(3) \Rightarrow a = 0,2 ; b = 0,2 ; c= 0,15\\ \%m_{Mg} = \dfrac{0,2.24}{18,6}.100\% = 25,81\%\\ \%m_{Al} = \dfrac{0,2.27}{18,6}.100\% = 29,03\%\\ \%m_{Fe} = 100\% - 25,81\% -29,03\% = 45,16\%\)
mik c.ơn trước
a)
$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
b) $n_{KMnO_4} = \dfrac{79}{158} = 0,5(mol)$
Theo PTHH : $n_{O_2} = \dfrac{1}{2}n_{KMnO_4} = 0,25(mol)$
$\Rightarrow V_{O_2} = 0,25.22,4 = 5,6(lít)$
c) $n_P = \dfrac{3,1}{31} = 0,1(mol)$
$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
Ta thấy : $n_P : 4 < n_{O_2} :5$ nên $O_2$ dư
$n_{P_2O_5} = \dfrac{1}{2}n_P = 0,05(mol)$
$m_{P_2O_5} = 0,05.142 = 7,1(gam)$
