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\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
Gọi số mol O2, CO2 là a, b
Có: \(\overline{M}=\dfrac{32a+44b}{a+b}=19,5.2=39\)
=> \(a=\dfrac{5}{7}b\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{\dfrac{5}{7}b}{\dfrac{5}{7}b+b}.100\%=41,67\%\\\%V_{CO_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{\dfrac{5}{7}b+b}.100\%=58,33\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=34,188\%\\\%m_{CO_2}=\dfrac{44b}{32a+44b}.100\%=65,812\%\end{matrix}\right.\)
thay a = \(\dfrac{5}{7}b\) thôi bn :)
\(\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=\dfrac{32.\dfrac{5}{7}b}{32.\dfrac{5}{7}b+44b}.100\%=34,188\%\)
1)
Coi \(n_X = 1(mol)\)
Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)
Ta có :
\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)
Vậy :
\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)
2)
\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)
gọi số mol N2 là xmol ,H2 là ymol
n khí = 22,4/22,4=1mol=>x + y =1(1)
theo bài ra hỗn hợp khí có tỉ khối với H2 là 3,6 nên ta có pt
x-4y=0(2)
từ (1) và (2) => x=0,8 mol : y=0,2 mol
=> mN2 = 0,8 * 14=11,2 g , mH2=0,2*2=0,2 g
=> m Khí = 11,2 + 0,4=11,6 g
=>%mN2=11,2*100/11,6=96,55%
=>%mH2=100-96,55=3,45%
\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(\overline{M_x}=24.2=48\)
\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\) 48 = \(\dfrac{16}{16}=1\)
\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)
1. \(m_{hh}=0,3.64+0,3.32=28,8g\)
2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)
\(\Rightarrow\%V_{O_2}=50\%\)
3. \(m_{SO_2}=0,3.64=19,2g\)
\(m_{O_2}=0,3.32=9,6g\)
Áp dụng quy tắc đường chéo:
\(a.\\ \Rightarrow\dfrac{V_{Cl_2}}{V_{O_2}}=\dfrac{15,6}{23,4}=\dfrac{2}{3}\\ \Rightarrow\left\{{}\begin{matrix}\%V_{Cl_2}=40\%\\\%V_{O_2}=60\%\end{matrix}\right.\)
\(b.\)
Ta có: \(\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{2}{3}\Leftrightarrow\dfrac{m_{Cl_2}}{m_{O_2}}=\dfrac{71.2}{32.3}=\dfrac{71}{48}\Leftrightarrow48m_{Cl_2}-71m_{O_2}=0\)
Mặt khác: \(m_{Cl_2}+m_{O_2}=5,95\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cl_2}=3,55\left(g\right)\\m_{O_2}=2,4\left(g\right)\end{matrix}\right.\)
Gọi số mol H2S, CO2 là a, b (mol)
\(\overline{M}=\dfrac{34a+44b}{a+b}=19,5.2=39\left(g/mol\right)\)
=> 5a = 5b
=> a = b
=> \(\left\{{}\begin{matrix}\%m_{H_2S}=\dfrac{34a}{34a+44b}.100\%=43,59\%\\\%m_{CO_2}=\dfrac{44b}{34a+44b}.100\%=56,41\%\end{matrix}\right.\)