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PTHH: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(2FeCl_3+Cu\rightarrow CuCl_2+2FeCl_2\)
Ta có: \(\left\{{}\begin{matrix}n_{FeCl_3}=2n_{Fe_2O_3}=2\cdot\dfrac{16}{160}=0,2\left(mol\right)\\n_{Cu}=\dfrac{32}{64}=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,5}{1}\) \(\Rightarrow\) Cu còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{CuCl_2}=0,1\left(mol\right)\\n_{FeCl_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuCl_2}=0,1\cdot135=13,5\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\end{matrix}\right.\)
a) CuO + 2HCl ⟶CuCl2 + 2H2O
6HCl + Fe2O3 → 2FeCl3 + 3H2O
Gọi x, y lần lượt là số mol CuO, Fe2O3
\(\left\{{}\begin{matrix}80x+160y=16\\135x+162,5.2y=29,75\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
=> \(\%m_{CuO}=\dfrac{0,1.80}{16}.100=50\%\)
\(\%m_{Fe_2O_3}=100-50=50\%\)
b) \(n_{HCl}=2n_{CuO}+6n_{Fe_2O_3}=0,5\left(mol\right)\)
=> \(CM_{HCl}=\dfrac{0,3}{0,1}=3M\)
a, \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 160y = 32 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{CuCl_2}=n_{Cu}=x\left(mol\right)\\n_{FeCl_3}=2n_{Fe_2O_3}=2y\left(mol\right)\end{matrix}\right.\) ⇒ 135x + 325y = 59,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2.80=16\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{CuO}+6n_{Fe_2O_3}=1\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{1}{0,5}=2\left(l\right)\)
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
$n_{Zn} = n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$m_{Zn} = 0,1.65 = 6,5(gam)$
$m_{ZnO} = 14,6 - 6,5 = 8,1(gam)$
c)
$n_{ZnO} = \dfrac{8,1}{81} = 0,1(mol)$
$n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,4(mol)$
$\Rightarrow V_{dd\ HCl} = \dfrac{0,4}{C_{M_{HCl}}}$
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
Theo PTHH :
$n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$\Rightarrow m_{Zn} = 0,2.65 = 13(gam)$
$\Rightarrow m_{ZnO} = m_{hh} - m_{Zn} = 8,8 - 13 = -4,2 < 0$(Sai đề)
