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a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
\(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)
c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)
\(n_{MgCl_2}=0,15.0,2=0,03(mol)\\ PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow +2NaCl\\ a,n_{Mg(OH)_2}=n_{MgCl_2}=0,03(mol)\\ \Rightarrow m_{\downarrow}=m_{Mg(OH)_2}=0,03.58=1,74(g)\\ b,n_{NaOH}=2n_{MgCl_2}=0,06(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,06}{0,3}=0,2M\\ c,PTHH:Mg(OH)_2\xrightarrow{t^o}MgO+H_2O\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=0,03(mol)\\ \Rightarrow m_{A}=m_{MgO}=0,03.40=1,2(g)\)
a) $CuSO_4 + 2NaOH \to Cu(OH)_2 + Na_2SO_4$
b) $n_{Cu(OH)_2} = n_{CuSO_4} = \dfrac{16}{160} = 0,1(mol)$
$m_{Cu(OH)_2} = 0,1.98 = 9,8(gam)$
c) $n_{NaOH} = 2n_{CuSO_4} = 0,2(mol) \Rightarrow C_{M_{NaOH}} = \dfrac{0,2}{0,1} = 2M$
PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
Ta có: \(n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2\left(M\right)\\m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\end{matrix}\right.\)
a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
b. Đổi 100ml = 0,1 lít
Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)
=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
a)
$Fe + CuSO_4 \to FeSO_4 + Cu$
Theo PTHH : $n_{Cu} = n_{CuSO_4} = 0,3.1 = 0,3(mol)$
$m_{Cu} = 0,3.64 = 19,2(gam)$
b) $n_{FeSO_4} = n_{CuSO_4} = 0,3(mol)$
$\Rightarrow m_{FeSO_4} = 0,3.152 = 45,6(gam)$
c) $FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4$
$n_{Fe(OH)_2} = n_{FeSO_4} = 0,3(mol)$
$m_{Fe(OH)_2} = 0,3.90 = 27(gam)$