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\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CaCO_3}=n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\)
a, \(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1------------->0,5
Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,5----->0,5
b, \(V_{O_2}=1.22,4=22,4\left(l\right)\)
c, \(m_{CaCO_3}=0,5.100=50\left(g\right)\)
$n_{Ba(OH)_2}= 0,2(mol)$
$n_{BaCO_3} = 0,15(mol)$
TH1 : $Ba(OH)_2$ dư
$Ba(OH)_2 + CO_2 \to BaCO_3 + H_2O$
$n_{CO_2} = n_{BaCO_3} = 0,15(mol) > n_{hh\ khí} = 0,05$(loại)
TH2 : Kết tủa bị hòa tan 1 phần
$n_{Ba(HCO_3)_2} = n_{Ba(OH)_2} - n_{BaCO_3} = 0,05(mol)$
$n_{CO_2} = n_{BaCO_3} + 2n_{Ba(HCO_3)_2} = 0,3(mol) >n_{hh}$
(Sai đề)
\(n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
=> nC = 0,075 (mol)
Có \(n_{CO_2}=n_C=0,075\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{4,2-0,075.44}{18}=0,05\left(mol\right)\)
=> nH = 0,1 (mol)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Bảo toàn O: \(n_{O\left(A\right)}=0,075.2+0,05-0,1.2=0\left(mol\right)\)
=> A chứa C, H
mA = mC + mH = 0,075.12 + 0,1.1 = 1 (g)
\(m_{tăng}=m_{H_2O}+m_{CO_2}=4,2\left(g\right)\\ n_{CaCO_3}=\dfrac{7,5}{100}=0,075\left(mol\right)\)
PTHH: Ca(OH)2 + CO2 ---> CaCO3 + H2O
0,075 0,075
\(\rightarrow m_{CO_2}=0,075.44=3,3\left(g\right)\\ \rightarrow m_{H_2O}=4,2-3,3=0,9\left(g\right)\\ \rightarrow n_{H_2O}=\dfrac{0,9}{18}=0,05\left(mol\right)\\ \rightarrow n_{O\left(sau.pư\right)}=0,05+0,075.2=0,1\left(mol\right)\\ n_{O\left(trong.O_2\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}n_C=0,075\left(mol\right)\\n_H=0,05.2=0,1\left(mol\right)\\n_O=0,1-0,1=0\left(mol\right)\end{matrix}\right.\)
=> mA = 0,075.12 + 0,1.1 + 0 = 1 (g)
Gọi $n_{Na} = a(mol)$
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : $0,5a + 1,5a = \dfrac{3,36}{22,4} = 0,15 \Rightarrow a = 0,075$
Vậy :
$m = 0,075.23 + 0,075.27 + 1,35 = 5,1(gam)$
Gọi nNa=a(mol)���=�(���)
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : 0,5a+1,5a=3,3622,4=0,15⇒a=0,0750,5�+1,5�=3,3622,4=0,15⇒�=0,075
Vậy :
m=0,075.23+0,075.27+1,35=5,1(gam)
a)
CTHH: FexOy
\(n_{Fe_xO_y}=\dfrac{16}{56x+16y}\left(mol\right)\)
PTHH: FexOy + yCO --to--> xFe + yCO2
\(\dfrac{16}{56x+16y}\)--------->\(\dfrac{16x}{56x+16y}\)
=> \(\dfrac{16x}{56x+16y}.56=16-4,8=11,2\)
=> \(\dfrac{x}{y}=\dfrac{2}{3}\Rightarrow Fe_2O_3\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3CO --to--> 2Fe + 3CO2
0,1------>0,3--------------->0,3
Ca(OH)2 + CO2 --> CaCO3 + H2O
0,3----->0,3
=> \(m_{CaCO_3}=0,3.100=30\left(g\right)\)
b) nCO (thực tế) = 0,3.110% = 0,33(mol)
=> VCO = 0,33.22,4 = 7,392(l)
CO+1/2O2------>CO2
x-----1/2x ----------x mol
H2 + CuO --------> Cu +H2O
0,3<--------------------0,3
=>y=0,3
ta có CO2 + Ca(OH)2 -->CaCO3 +H2O
0,2<-------------------- 0,2
=> x=0,2 mol
tỉ lệ về số mol cũng là tỉ lệ thể tích
%VCO=(0,2/0,5).100%=40% , %VH2=60%.
nCH4 = 11.2/22.4 = 0.5 (mol)
CH4 + 2O2 -to-> CO2 + 2H2O
0.5____________0.5
CO2 + Ca(OH)2 => CaCO3 + H2O
0.5_______________0.5
mCaCO3 = 0.5*100 = 50 (g)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 +2H_2O\\ CO_2 +C a(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} = \dfrac{11,2}{22,4} = 0,5(mol)\\ m = 0,5.100 = 50(gam)\)