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\(a,n_{FeS_2}=\dfrac{m_{FeS_2}}{M_{FeS_2}}=\dfrac{6}{120}=0,05\left(mol\right)\\ 4FeS_2+11O_2\rightarrow\left(t^o,xt\right)2Fe_2O_3+8SO_2\uparrow\\ n_{Fe_2O_3}=\dfrac{2}{4}.n_{FeS_2}=\dfrac{2}{4}.0,05=0,025\left(mol\right)\\ \Rightarrow m_{Fe_2O_3}=160.0,025=4\left(g\right)\\ n_{SO_2}=\dfrac{8}{4}.n_{FeS_2}=\dfrac{8}{4}.0,05=0,1\left(mol\right)\\ \Rightarrow m_{SO_2}=0,1.64=6,4\left(g\right)\\ \Rightarrow m_{sp}=m_{Fe_2O_3}+m_{SO_2}=4+6,4=10,4\left(g\right)\\ b,n_{O_2}=\dfrac{11}{4}.n_{FeS_2}=\dfrac{11}{4}.0,05=0,1375\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,1375.22,4=3,08\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=3,08.5=15,4\left(l\right)\)
\(pthh:4FeS_2+11O_2\overset{t^o}{--->}2Fe_2O_3+8SO_2\uparrow\)
a. Ta có: \(n_{FeS_2}=\dfrac{6}{120}=0,05\left(mol\right)\)
Theo pt: \(n_{O_2}=\dfrac{11}{4}.n_{FeS_2}=\dfrac{11}{4}.0,05=0,1375\left(mol\right)\)
\(\Rightarrow m_{sản.phẩm.thu.được}=6+0,1375.32=10,4\left(g\right)\)
b. Ta có: \(V_{O_2}=0,1375.22,4=3,08\left(lít\right)\)
Mà: \(V_{O_2}=\dfrac{1}{5}V_{kk}\)
\(\Rightarrow V_{kk}=3,08.5=15,4\left(lít\right)\)
$n_{C_2H_2} = \dfrac{6,72}{22,4} = 0,3(mol) ; n_{O_2} = 0,5(mol)$
$2C_2H_2 + 5O_2 \xrightarrow{t^o} 4CO_2 + 2H_2O$
Ta thấy :
$n_{C_2H_2} : 2 > n_{O_2} : 5$ nên $C_2H_2$ dư
Theo PTHH :
$n_{C_2H_2\ pư} = \dfrac{5}{2} = 0,2(mol)$
$n_{CO_2} = 0,4(mol) ; n_{H_2O} = 0,2(mol)$
Suy ra :
$m_{C_2H_2\ dư} = (0,3 - 0,2).26 = 2,6(gam)$
$m_{CO_2} = 0,4.44 = 17,6(gam)$
$m_{H_2O} = 0,2.18 = 3,6(gam)$
nFeS2 = 120/120 = 1 (mol)
PTHH: 4FeS2 + 11O2 -> (t°) 2Fe2O3 + 8SO2
Mol: 1 ---> 2,75 ---> 0,5 ---> 2
VO2 = 2,75/(100% - 10%) . 22,4 = 616/9 (l)
msp = (0,5 . 160 + 8 . 64) . 80% = 437,6 (g)
nFeS2 = 120/120 = 1 (mol)
PTHH: 4FeS2 + 11O2 -> (t°) 2Fe2O3 + 8SO2
Mol: 1 ---> 2,75 ---> 0,5 ---> 2
VO2 = 2,75/(100% - 10%) . 22,4 = 616/9 (l)
msp = (0,5 . 160 + 8 . 64) . 80% = 437,6 (g)
4FeS2+11O2-to>2Fe2O3+8SO2
1-------------2,75-------0,5-------2 mol
n FeS2=\(\dfrac{120}{120}=1mol\)
=>VO2=2,75.\(\dfrac{110}{100}\).32=96,8g
H=80%
=>m Fe2O3=0,5.160.\(\dfrac{80}{100}\)=64g
9,6 S phải ko bn
\(n_S=\dfrac{m}{M}=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(PTHH:S+O_2-^{t^o}>SO_2\)
tỉ lệ: 1 : 1 : 1
n(mol): 0,3--->0,3---->0,3
\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,3\cdot22,4=6,72\left(l\right)\\ V_{kk}=6,72:\dfrac{1}{5}=33,6\left(l\right)\\ V_{SO_2\left(dktc\right)}=n\cdot22,4=0,3\cdot22,4=6,72\left(l\right)\)
a)
\(\left\{{}\begin{matrix}n_{C_2H_2}+n_{CH_4}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\\dfrac{n_{C_2H_2}}{n_{CH_4}}=2\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{C_2H_2}=0,4\left(mol\right)\\n_{CH_4}=0,2\left(mol\right)\end{matrix}\right.\)
PTHH: 2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,4----->1------------->0,8
CH4 + 2O2 --to--> CO2 + 2H2O
0,2-->0,4---------->0,2
=> VO2 = (1+0,4).22,4 = 31,36(l)
=> VCO2 = (0,8 + 0,2).22,4 = 22,4 (l)
b)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
2,8<---------------------------------1,4
=> \(m_{KMnO_4\left(PTHH\right)}=2,8.158=442,4\left(g\right)\)
=> mKMnO4 (thực tế) = 442,4 : 80% = 553(g)
\(n_{C_2H_2}=\dfrac{2,6}{26}=0,1\left(mol\right)\\ 2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\\ a,n_{O_2}=\dfrac{5}{2}.n_{C_2H_2}=\dfrac{5}{2}.0,1=0,25\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{CO_2}=\dfrac{4}{2}.n_{C_2H_2}=\dfrac{4}{2}.0,1=0,2\left(mol\right)\\ \Rightarrow m_{CO_2}=0.2.44=8,8\left(g\right)\\ n_{H_2O}=n_{C_2H_2}=0,1\left(mol\right)\\ \Rightarrow m_{H_2O}=0,1.18=1,8\left(g\right)\\ \Rightarrow m_{sp}=m_{CO_2}+m_{H_2O}=8,8+1,8=10,6\left(g\right)\)