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a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
(mol)_____0,2____0,2______0,2____0,2__
\(a.V_{H_2}=22,4.0,2=4,48\left(l\right)\)
\(b.m_{ddH_2SO_4}=\dfrac{0,2.98.100}{24,5}=80\left(g\right)\)
\(c.m_{ddspu}=13+80-0,2.2=92,6\left(g\right)\\ \Rightarrow C\%_{ddspu}=\dfrac{0,2.136}{92,6}.100=29,4\left(\%\right)\)
`Fe_2O_3+3H_2SO_4->Fe_2(SO_4)_3+3H_2O`
0,0625----------0,1875---------0,0625 mol
`->n_(Fe_2O_3)=10/160=0,0625mol`
`->m_(Fe_2(SO_4)_3)=0,0625.400=25g`
`->C%(H_2SO_4)=((0,1875.98)/(450)).100%=4,083%`
`#YBtran<3`
\(n_{Fe_2O_3}=\dfrac{10}{160}=0,0625\left(mol\right)\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,0625\left(mol\right)\\ a,m=m_{Fe_2\left(SO_4\right)_3}=400.0,0625=25\left(g\right)\\ b,n_{H_2SO_4}=3.0,0625=0,1875\left(mol\right)\\ C\%_{ddH_2SO_4}=\dfrac{0,1875.98}{450}.100\%\approx4,083\%\)
\(n_{Mg}=\dfrac{10,8}{24}=0,45\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
0,45 0,45 0,45
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\\
C\%_{H_2SO_4}=\dfrac{44,1}{176,4}.100\%=25\%\\
V_{H_2}=0,45.22,4=10,08\left(l\right)\)
a, \(m_{HCl}=150.7,3\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Theo PT: \(n_{Mg}=n_{MgCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\)
\(m_{Mg}=0,15.24=3,6\left(g\right)\)
b, \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c, Ta có: m dd sau pư = 3,6 + 150 - 0,15.2 = 153,3 (g)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,15.95}{153,3}.100\%\approx9,3\%\)
a) \(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,02->0,02------------------>0,02
b) \(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
c) \(C\%_{H_2SO_4}=\dfrac{0,02.98}{100}.100\%=1,96\%\)
d) \(n_{CuO}=\dfrac{0,8}{80}=0,01\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,01 < 0,02 => H2 dư
Theo pthh: nCu = nCuO = 0,01 (mol)
=> mCu = 0,01.64 = 0,64 (g)
\(a) n_{Fe_2O_3}= \dfrac{8}{160} = 0,05(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{FeCl_3} = 2n_{Fe_2O_3} = 0,1(mol)\\ m_{FeCl_3} = 0,1.162,5 = 16,25(gam)\\ b) n_{HCl} = 6n_{Fe_2O_3} = 0,05.6 = 0,3(mol)\\ V_{dd\ HCl} = \dfrac{0,3}{0,5} = 0,6(lít)\\ c) V_{dd\ sau\ pư} = V_{dd\ HCl} =0,6(lít)\\ C_{M_{FeCl_3}} = \dfrac{0,1}{0,6} = 0,167M\)
PTHH:\(Fe_2O_3+HCl\rightarrow FeCl_3+3H_2O\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
a, Bảo toàn nguyên tố Fe:
\(n_{FeCl_3}=n_{Fe}=2n_{Fe_2O_3}=2.0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=162,5.0,1=16,25\left(g\right)\)
b, Bảo toàn nguyên tố Cl:
\(n_{Hcl}=n_{Cl}=3n_{FeCl_3}=3.0,1=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{n_{HCL}}{C_M}=\dfrac{0,3}{0,5}=0,6\left(l\right)\)
c,\(C_{M_{FeCl_3}}=\dfrac{n_{FeCl_3}}{V_{ddFeCl_3}}=\dfrac{0,1}{0,6}=0,17M\)
a, PTPƯ: SO3 + H2O ---> H2SO4
nSO3=\(\dfrac{2,24}{22,4}=0,1mol\)
1 mol SO3 ---> 0,1 mol H2SO4
nên 0,1 mol SO3 ---> 0,1 mol H2SO4
CM H2SO4=\(\dfrac{0,1}{0,5}\)=0,2 M
b, PTPƯ: Zn + H2SO4 ---> ZnSO4 + H2
1 mol H2SO4 ---> 1 mol Zn
nên 0,1 mol H2SO4 ---> 0,1 mol Zn
mZn=0,1.65=6,5 g
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,305 0,305 0,305 0,305
\(n_{H_2}=\dfrac{6,832}{22,4}=0,305\left(mol\right)\)
\(a,m_{H_2SO_4}=98.0,305=29,89\left(g\right)\)
\(m_{ddH_2SO_4}=\dfrac{28,89}{12,5}.100\approx199,3\left(g\right)\)
\(m_{Mg}=24.0,305=7,32\left(g\right)\)
\(m_{H_2}=0,305.2=0,61\left(g\right)\)
Áp dụng định luật bảo toàn khổi lượng , ta có :
\(m_{MgSO_4}=\left(199,3+7,32\right)-0,61=206,01\left(g\right)\)
\(b,m_{MgSO_4}=0,305.120=36,6\left(g\right)\)
\(C\%_{MgSO_4}=\dfrac{36,6}{206,01}.100\%\approx17,8\%\)