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\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: \(Zn+Cl_2\underrightarrow{t^o}ZnCl_2\)
_____0,05-->0,05->0,05______(mol)
\(2Al+3Cl_2\underrightarrow{t^o}2AlCl_3\)
0,1--->0,15-->0,1_____________(mol)
=> m = \(0,05.136+0,1.133,5=20,15\left(g\right)\)
\(V_{Cl_2}=\left(0,05+0,15\right).22,4=4,48\left(l\right)\)
Một cách hơi khác nha ;-;
\(n_{Zn}=\dfrac{m}{M}=0,05\left(mol\right)n_{Al}=\dfrac{m}{M}=0,1\left(mol\right)\)
\(Bte:2n_{Cl_2}=2n_{Zn}+3n_{Al}=0,4\)
\(\Rightarrow n_{Cl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{Cl_2}=n.22,4=4,48\left(l\right)\)
Ta có : \(m_M=m_{KL}+m_{Cl}=3,25+2,7+0,2.71=20,15\left(g\right)\)
Vậy ..
a)
$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + H_2O$
$2Fe + 6H_2SO_4 \to Fe_2(SO_4)_3 + 3SO_2 + 6H_2O$
b) n Cu =a (mol) ; n Fe = b(mol)
=> 64a + 56b = 12(1)
n SO2 = a + 1,5b = 5,6/22,4 = 0,25(2)
(1)(2) suy ra a = b = 0,1
%m Cu = 0,1.64/12 .100% = 53,33%
%m Fe = 100% -53,33% = 46,67%
c)
n CuSO4 = a = 0,1(mol)
n Fe2(SO4)3 = 0,5a = 0,05(mol)
m muối = 0,1.160 + 0,05.400 = 36(gam)
d) n H2SO4 = 2n SO2 = 0,5(mol)
V H2SO4 = 0,5/2 = 0,25(lít)
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)
