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PTHH: 2CH3COOH+Na2CO3→2CH3COONa+CO2+H2O
Ta có:
nCO2=3,36/22,4=0,15mol
=> nCH3COOH=2nCO2=0,3mol
=> VCH3COOH=0,3/0,5=0,6l
=> nCH3COONa=2nCO2=0,3mol
=> mCH3COONa=0,3.82=24,6g
nNa2CO3 = nCO2 = 0,15mol
=> C%Na2CO3 = (0,15.106)/300.100%=5,3%
Rượu etylic \(C_2H_5OH\)
Axit axetic \(CH_3COOH\)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)
0,2 0,1 0,2 0,1 0,1
\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)
\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)
a)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
0,2<----------0,1<-------------0,2<-------0,1
=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)
\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)
b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)
\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)
a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)
\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na2CO3 hết, CH3COOH dư
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15-------->0,3-------------->0,3------->0,15
=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)
b) mdd sau pư = 120 + 53 - 0,15.44 = 166,4 (g)
=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)
Đề là: nhỏ dung dịch AgNO3/NH3 vào C6H12O6
===> Tính thể tích CH3COOH???
a) PTHH: Zn + H2SO4 -> ZnSO4 + H2
nH2= 0,15(mol)
=> nZn=nH2SO4=nZnSO4=nH2=0,15(mol)
b) mZn=0,15.65=9,75(g)
c) CMddH2SO4= 0,15/ 0,05=3(M)
d) mZnSO4= 161. 0,15=24,15(g)
a)
$n_{Al} = \dfrac{8,1}{27} = 0,3(mol)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{H_2} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
b) $n_{HCl} = 3n_{Al} = 0,9(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,9.36,5}{3,65\%} = 900(gam)$
c)
$m_{dd\ sau\ pư}= 8,1 + 900 - 0,45.2 = 907,2(gam)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,15(mol)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{907,2}.100\% = 5,65\%$
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
nCO2= 0.15 mol
CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0.15_________0.15_________0.15______0.15
VddCH3COOH= 0.15/0.5=0.3 l
mCH3COONa = 12.3g
C%NaHCO3= 12.6/300*100%=4.2%