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\(n_{CuCl_2}=2.0,2=0,4(mol)\\ n_{NaOH}=2.0,2=0,4(mol)\\ a,CuCl_2+2NaOH\to Cu(OH)_2+2NaCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ b,\dfrac{n_{CuCl_2}}{1}>\dfrac{n_{NaOH}}{2}\Rightarrow CuCl_2\text{ dư}\\ \Rightarrow n_{CuO}=0,2(mol)\\ \Rightarrow m_{CuO}=0,2.80=16(g)\\ c,n_{CuCl_2(dư)}=0,4-0,2=0,2(mol)\\n_{NaCl}=0,2(mol)\\ \Rightarrow m_{CuCl_2(dư)}=0,2.135=27(g)\\ m_{NaCl}=0,2.58,5=11,7(g)\)
PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Ta có: \(n_{CuCl_2}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}\\n_{NaOH}=0,4\left(mol\right)=n_{NaCl}\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu\left(OH\right)_2}=0,2\cdot98=19,6\left(g\right)\\m_{CuO}=0,2\cdot80=16\left(g\right)\\m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\C\%_{NaOH}=\dfrac{0,4\cdot40}{200}\cdot100\%=8\%\end{matrix}\right.\)
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
\(n_{NaOH}=\dfrac{200.10\%}{40}=0,5\left(mol\right)\)
\(PTHH:CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
bđ: 0,3 0,5
pứ: 0,25 0,5 0,5 0,25
[ ]: 0,05 0 0,5 0,25
\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
(mol) 0,25 0,25
\(a.m_C=80.0,25=20\left(g\right)\)
\(b.m_{NaCl}=58,5.0,5=29,25\left(g\right)\\ m_{Cu\left(OH\right)_2}=0,25.98=24,5\left(g\right)\\ m_{CuCl_2\left(du\right)}=135.0,05=6,75\left(g\right)\)
\(c.m_{ddspu}=100+200-24,5=275,5\left(g\right)\\ C\%_{ddCuCl_2\left(du\right)}=\dfrac{135.0,05}{275,5}.100=2,45\left(\%\right)\\ C\%_{ddNaCl}=\dfrac{0,5.58,5}{275,25}.100=10,62\left(\%\right)\)
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
Lập tỉ lệ : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)=> Sau phản ứng NaOH dư
\(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
Dung dịch nước lọc gồm NaCl (0,4_mol); NaOH dư ( 0,1 mol)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\)
\(a=m_{CuO}=0,2.80=16\left(g\right)\)
b) \(m_{NaCl}=0,4.58,5=23,4\left(g\right);m_{NaOH}=0,1.40=4\left(g\right)\)
Đề có sai không vậy bạn......
CuCl2 +2 NaOH--->Cu(OH)2+2 NaCl(1)
Cu(OH)2----->CuO +H2O(2)
a) Ta có
n\(_{NaOH}=\frac{20}{40}=0,5mol\)
=>CuCl2 dư
Theo pthh1
n\(_{Cu\left(OH\right)2}=\frac{1}{2}n_{NaOH}=0,25mol\)
Theo pthh 2
n\(_{CuO}=n_{Cu\left(OH\right)2}=0,25mol\)
m\(_{CuO}=m\)chất rắn C =0,25.80=20(g)
b)dd B gồm CuCl 2 dư và Na Cl
Theo pthh1
n\(_{CuCl2}=\frac{1}{2}n_{NaOH}=0,25mol\)
n\(_{CuCl2}dư=\)\(2-0,25=1,75mol\)
m\(_{CuCl2}=1,75.135=236,259\left(g\right)\)
Theo PTHH1
n\(_{NaCl}=n_{NaOH}=0,25mol\)
m\(_{NaCl}=0,25.58,5\left(g\right)\)
Chúc bạn hok tốt
Nhớ tích cho mk nhé