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a.\(n_{hh}=\dfrac{6,72}{22,4}=0,3mol\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x x ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
y 2y ( mol )
\(n_{CaCO_3}=\dfrac{40}{100}=0,4mol\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
0,4 0,4 ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,3\\x+2y=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%V_{CH_4}=\dfrac{0,2}{0,3}.100=66,67\%\)
\(\%V_{C_2H_4}=100\%-66,67\%=33,33\%\)
b.\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(m_{Br_2}=0,1.160:10\%=160g\)
\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,05
Suy ra:
\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)
b)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)
\(a) C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = n_{C_2H_4Br_2} = \dfrac{18,8}{188} = 0,1(mol)\\ V_{C_2H_4} = 0,1.22,4 = 2,24(lít)\\ V_{CH_4} = 5,6 -2,24 = 3,36(lít)\\ b) m_{Br_2} = 0,1.180 = 18(gam) \)
\(n_{hh}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{Br_2}=\dfrac{48}{160}=0,3mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,2\\2x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,1}{0,2}.100=50\%\\\%V_{C_2H_4}=100\%-50\%=50\%\end{matrix}\right.\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,1<--0,1
=> \(\%V_{C_2H_4}=\dfrac{0,1.22,4}{22,4}=10\%\)
=> %VCH4 = 100% - 10% = 90%
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Ta có: \(\left\{{}\begin{matrix}n_{hhkhí}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{C_2H_4Br_2}=\dfrac{18,8}{188}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{C_2H_4}=n_{CH_4}=n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=V_{C_2H_4}=0,1\cdot22,4=2,24\left(l\right)\\m_{Br_2}=0,1\cdot160=16\left(g\right)\end{matrix}\right.\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
a, Ta có: \(n_{hhk}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(n_{C_2H_4Br_2}=\dfrac{18,8}{188}=0,1\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1}{0,2}.100\%=50\%\\\%V_{CH_4}=50\%\end{matrix}\right.\)
b, Theo PT: \(n_{Br_2}=n_{C_2H_4Br_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Br_2}=0,1.160=16\left(g\right)\)
Bạn tham khảo nhé!