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nCO phản ứng = nCO2 = nFe = nO = 0,1
→ mFe = 5,6g
nCO2 dư = 0,2 - 0,1 = 0,1
→ %VCO2 = 50%
FeO + CO -> Fe + CO2
nCO=0,2(mol)
Đặt nFeO tham gia PƯ=a
Ta có:
72a-56a=1,6
=>a=0,1
Theo PTHH ta có:
nFe=nCO2=nFeO tham gia PƯ=0,1(mol)
mFe=56.0,1=5,6(g)
%VCO2=\(\dfrac{0,1}{0,2}.100\%=50\%\)
%VCO=100-50=50%
Đặt :
nFeO = x mol
FeO + CO -to-> Fe + CO2
x_____x_______x_____x
m giảm = mFeO - mFe = 1.6
<=> 72x - 56x = 1.6
=> x = 0.1
mFe = 0.1*56 = 5.6 g
nCO dư = 0.2 - 0.1 = 0.1 mol
nCO2 = 0.1 mol
Vì : %V = %n
%CO = %CO2 = 0.1/0.2 *100% = 50%
Đặt \(n_{FeO}=x\left(mol\right)\)
\(FeO+CO\underrightarrow{t^o}Fe+CO_2\)
x → x
\(m_{giảm}=m_{FeO}-m_{Fe}=1,6\)
\(\Leftrightarrow72x-56x=1,6\)
\(\rightarrow x=0,1\)\(\rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)
\(n_{CO}dư=0,2-0,1=0,1\left(mol\right)\)
→\(n_{CO_2}=0,1\left(mol\right)\)
mà \(\%V=\%n\)
%CO=%CO2\(\frac{0,1}{0,2}\).100%=50%
a) Ta có: nH2=4,48/22,4=0,2(mol)
PTHH: Fe +2 HCl -> FeCl2 + H2
0,2________0,4______0,2__0,2(mol)
mFe=0,2.56=11,2(g)
=> %mFe= (11,2/17,6).100=63,636%
=> %mCu= 36,364%
b) Fe2O3 + 3 H2 -to-> 2 Fe + 3 H2O
Ta có: nH2=0,2(mol) => nFe=2/3. 0,2= 2/15(mol)
=> mFe= 2/15 . 56=7,467(g)
Số moll của khí hidro ở dktc
nH2 = \(\dfrac{V_{H2}}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : Fe + 2HCl → FeCl2 + H2\(|\)
1 2 1 1
0,2 0,2
a) Số mol của sắt
nFe = \(\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
Khối lượng của sắt
mFe = nFe . MFe
= 0,2. 56
= 11,2 (g)
Khối lượng của đồng
mCu = 17,6 - 11,2
= 6,4 (g)
0/0Fe = \(\dfrac{m_{Fe}.100}{m_{hh}}=\dfrac{11,2.100}{17,6}=63,64\)0/0
0/0Cu = \(\dfrac{m_C.100}{m_{hh}}=\dfrac{6,4.100}{17,6}=36,36\)0/0
b) 3H2 + Fe2O3 → (to) 2Fe + 3H2O\(|\)
3 1 2 3
0,2 0,13
Số mol của sắt
nFe = \(\dfrac{0,2.2}{3}=0,13\left(mol\right)\)
Khối lượng của sắt
mFe = nFe . MFe
= 0,13 . 56
= 7,28 (g)
Chúc bạn học tốt
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{CuO}=\dfrac{3,2}{80}=0,04\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{H_2O}=n_{CuO}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,04.64=2,56\left(g\right)\\m_{H_2O}=0,04.18=0,72\left(g\right)\end{matrix}\right.\)
b, PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Ta có: \(n_{Fe_3O_4}=\dfrac{10,8}{232}=\dfrac{27}{580}\left(mol\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{\dfrac{27}{580}}{1}< \dfrac{0,2}{4}\), ta được H2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{H_2\left(pư\right)}=n_{H_2O}=4n_{Fe_3O_4}=\dfrac{27}{145}\left(mol\right)\\n_{Fe}=3n_{Fe_3O_4}=\dfrac{81}{580}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,2-\dfrac{27}{145}=\dfrac{2}{145}\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=\dfrac{2}{145}.2\approx0,0276\left(g\right)\)
\(m_{H_2O}=\dfrac{27}{145}.18\approx3,35\left(g\right)\)
\(m_{Fe}=\dfrac{81}{580}.56\approx7,82\left(g\right)\)
Bạn tham khảo nhé!
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
a) PTHH : \(FeO+H_2-t^o->Fe+H_2O\)
\(CuO+H_2-t^o->Cu+H_2O\)
Đặt \(\hept{\begin{cases}n_{FeO}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{cases}}\) => \(72x+80y=11,2\left(I\right)\)
Có : \(m_{O\left(lấy.đi\right)}=m_{giảm}=1,92\left(g\right)\)
=> \(n_{O\left(lấy.đi\right)}=\frac{1,92}{16}=0,12\left(mol\right)\) Vì H% = 80% => Thực tế : \(n_{O\left(hh\right)}=\frac{0,12}{80}\cdot100=0,15\left(mol\right)\)
BT Oxi : \(x+y=0,15\left(II\right)\)
Từ (I) và (II) suy ra : \(\hept{\begin{cases}x=0,1\\y=0,05\end{cases}}\)
=> \(\hept{\begin{cases}m_{FeO}=7,2\left(g\right)\\m_{CuO}=4\left(g\right)\end{cases}}\)
b) PTHH : \(Fe+H_2SO_4-->FeSO_4+H_2\)
BT Fe : \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
Theo pthh : \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
=> \(V_{H_2}=2,24\left(l\right)\)
BT Cu : \(n_{Cu}=n_{CuO}=0,05\left(mol\right)\)
=> \(m_{CR\left(ko.tan\right)}=0,05\cdot64=3,2\left(g\right)\)
\(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02mol\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\)
\(Fe_3O_4+4H_2\rightarrow3Fe+4H_2O\)
0,02 0,4 0 0
0,02 0,08 0,06 0,08
0 0,32 0,06 0,08
b)\(m_{Fe}=0,06\cdot56=3,36g\)
\(m_{H_2O}=0,08\cdot18=1,44g\)
c)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,06 0,5 0 0
\(\Rightarrow\)Tính theo \(Fe\)
\(\Rightarrow V_{H_2}=0,06\cdot22,4=1,344l\)
\(n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\\ FeO+2HCl\rightarrow FeCl_2+H_2O\\ n_{FeO}=n_{FeCl_2}=n_{H_2O}=\dfrac{0,8}{2}=0,4\left(mol\right)\\ a,m_{FeO}=72.0,4=28,8\left(g\right)\\ b,C1:m_{sp}=m_{FeO}+m_{HCl}=28,8+29,2=58\left(g\right)\\ C2:m_{sp}=m_{FeCl_2}+m_{H_2O}=127.0,4+18.0,4=58\left(g\right)\)
\(a.n_{HCl}=0,8\left(mol\right)\\ FeO+2HCl\rightarrow FeCl_2+H_2O\\ n_{FeO}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\\ m_{FeO}=0,4.72=28,8\left(g\right)\\ b.n_{FeCl_2}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\\ m_{FeCl_2}=0,4.127=50,8\left(g\right)\\ n_{H_2O}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\\ \Rightarrow m_{H_2O}=0,4.18=7,2\left(g\right)\)
$FeO + CO \xrightarrow{t^o} Fe + CO_2$
Theo PTHH : $n_{FeO} = n_{CO\ pư} = n_{Fe} = n_{CO_2} = a(mol)$
$\Rightarrow m_{giảm} = m_{FeO} - m_{Fe} = 72a -56a = 16a = 1,6(gam)$
$\Rightarrow a = 0,1(mol)$
$m_{Fe} = 0,1.56 = 5,6(gam)$
$n_{CO\ dư} = 0,2 - 0,1 = 0,1(mol)$
$\%V_{CO\ dư} = \%V_{CO_2} = \dfrac{0,1}{0,1 + 0,1}.100\% = 50\%$
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