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\(a) 4Na + O_2 \xrightarrow{t^o} 2Na_2O\\ b) n_{Na} = \dfrac{4,6}{23} = 0,2(mol)\\ n_{O_2} = \dfrac{1}{4}n_{Na} = 0,05(mol)\\ V_{O_2} = 0,05.22,4 = 1,12(lít)\\ c) Na_2O + H_2O \to 2NaOH\\ n_{NaOH} = n_{Na} = 0,2(mol)\\ C\%_{NaOH} = \dfrac{0,2.40}{160}.100\% = 5\%\\ d)\)
\(n_{Na\ thêm} = x(mol)\\ 2Na + 2H_2O \to 2NaOH + H_2\\ n_{NaOH} = n_{Na} = x(mol)\\ n_{H_2} =0,5x(mol)\\ \Rightarrow m_{dd} = 23x + 160 -0,5x.2 = 22x + 160(gam)\\ \Rightarrow C\% = \dfrac{0,2.40 + 40x}{22x + 160}.100\% = 5\% + 5\%\\ \Rightarrow x = \dfrac{40}{189}\\ m_{Na} = \dfrac{40}{189}.23 = 4,87(gam)\)
\(n_{Na}=\dfrac{4.6}{23}=0.2\left(mol\right)\)
\(4Na+O_2\underrightarrow{^{t^0}}2Na_2O\)
\(0.2.....0.05.........0.1\)
\(V_{O_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(0.1.......................0.2\)
\(m_{NaOH}=0.2\cdot40=8\left(g\right)\)
\(C\%_{NaOH}=\dfrac{8}{160}\cdot100\%=5\%\)
Để C% tăng thêm 5%
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(a...............a.......0.5a\)
\(m_{NaOH}=40a\left(g\right)\)
\(m_{dd_{NaOH}}=23a+160-0.5a\cdot2=22a+160\left(g\right)\)
\(C\%_{NaOH}=\dfrac{40a+8}{22a+160}\cdot100\%=5\%\)
\(\Rightarrow a=0\)
=> Sai đề
Ta có : \(n_K=\dfrac{m}{M}=\dfrac{3,9}{39}=0,1\) (mol)
\(n_{H_2O}=\dfrac{m}{M}=\dfrac{96,2}{18}=5,34\)(mol)
Phương trình hóa học :
2K + 2H2O ---> 2KOH + H2
2 : 2 : 2 : 1
Nhận thấy \(\dfrac{n_K}{n_{H_2O}}=\dfrac{0,1}{5,34}< \dfrac{2}{2}\)
=> Kali hết , nước dư
=> \(n_{H_2}=\dfrac{n_K}{2}=0,05\) (mol)
=> Thể tích khí H2 : V = n.22,4 = 0,05.22,4 = 1,12(l)
Lại có \(n_{KOH}=0,1\) (mol) => \(m_{KOH}=0,1.56=5,6\) (g)
\(m_{H_2}=0,05.2=0,1\left(g\right)\)
Nồng độ phần trăm của Base thu được :
\(C\%=\dfrac{m_{KOH}}{m_{dd}-m_{H_2}}=\dfrac{5,6}{96,2+3,9-0,1}=0,056=5,6\%\)
a,\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right);n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
PTHH: 2Na + 2H2O → 2NaOH + H2
Mol: 0,2 0,1
PTHH: 2K + 2H2O → 2KOH + H2
Mol: 0,1 0,05
b, \(n_{H_2}=0,1+0,05=0,15\left(mol\right)\)
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c,mdd sau pứ=4,6+3,9+91,5-0,15.2=99,7 (g)
\(\%m_{NaOH}=\dfrac{0,2.40.100\%}{99,7}=8,02\%\)
\(\%m_{KOH}=\dfrac{0,1.56.100\%}{99,7}=5,62\%\)
Bài 3 :
\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
a) Pt : \(2Na+2H_2O\rightarrow2NaOH+H_2|\)
2 2 2 1
0,2 0,2 0,1
\(2K+2H_2O\rightarrow2KOH+H_2|\)
2 2 2 1
0,1 0,1 0,05
b) \(n_{H2\left(tổng\right)}=0,1+0,05=0,15\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
c) \(n_{NaOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
⇒ \(m_{NaOH}=0,2.40=8\left(g\right)\)
\(n_{KOH}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)
⇒ \(m_{KOH}=0,1.56=5,6\left(g\right)\)
\(m_{ddspu}=8,5+91,5-\left(0,15.2\right)=99,7\left(g\right)\)
\(C_{NaOH}=\dfrac{8.100}{99,7}=8,02\)0/0
\(C_{KOH}=\dfrac{5,6.100}{99,7}=5,62\)0/0
Chúc bạn học tốt
a)
2K + 2H2O --> 2KOH + H2
dd A là dd bazo nên quỳ tím đổi màu xanh
b)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
PTHH: 2K + 2H2O --> 2KOH + H2
0,1----------->0,1---->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
c) mdd = 3,9 + 36,2 - 0,05.2 = 40 (g)
=> \(C\%=\dfrac{0,1.56}{40}.100\%=14\%\)
\(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\\
n_{H_2O}=\dfrac{36,2}{18}=2\left(mol\right)\\
pthh:2K+2H_2O\rightarrow2KOH+H_2\\
ltl:\dfrac{0,1}{2}< \dfrac{2}{2}\)
=> nước dư
a) dd A là bazo => làm QT chuyển xanh
\(2K+2H_2O\rightarrow2KOH+H_2\)
0,1 0,1
\(V_{H_2}=0,1.22,4=2,24L\)
\(a,C\%_{KOH}=\dfrac{28}{140}.100\%=20\%\\ b,C\%_{KOH}=\dfrac{80}{80+320}.100\%=20\%\)
n Zn= 19,5/65=0,3 (mol).
PTPƯ: Zn(0.3) + HCl(0.6) ----> ZnCl2(0.3) + H2(0,3)
mHCl=0,6.36.5=21.9(g)
a) C%HCl= 21.9/300.100%=7,3%
b) VH2=0,3.22,4=6,72(lít)
c) mH2=0,3.2=0,6(g)
mZnCl2=0,3.136=40,8(g)
mddZnCl2 =(19,5+300)-0,6=318,9(g)
C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(a,V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(b,m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
\(c,m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{ddMgCl_2}=4,8+146-\left(0,2.2\right)=150,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{150,4}.100\%\approx12,63\%\)
2.
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
\(2K+2H_2O\rightarrow2KOH+H_2\uparrow\)
0,2 0,2 0,1
\(m_{KOH}=0,2.56=11,2\left(g\right)\)
\(m_{ddKOH}=7,8+100-\left(0,1.2\right)=107,6\left(g\right)\)
\(C\%=\dfrac{11,2}{107,6}.100\%\approx10,4\%\)
\(n_K=\frac{3,9}{39}=0,1\left(mol\right)\)
PTHH: K + 2Cl\(\rightarrow\) KCl2
0,1 \(\rightarrow\) 0,05 (mol)
VCl= 0,05.35,5=1,775(l)
K hóa trị 1, Cl cũng hóa trị 1 mà lại có công thức KCl2 là sao???