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Sửa đề : 24.8 (g) Na2O
\(n_{Na_2O}=\dfrac{24.8}{62}=0.4\left(mol\right)\)
\(n_{HNO_3\left(dư\right)}=\dfrac{50.4}{63}=0.8\left(mol\right)\)
\(Na_2O+2HNO_3\rightarrow2NaNO_3+H_2O\)
\(0.4............0.8..............0.8...........0.4\)
\(m_{NaNO_3}=0.8\cdot85=68\left(g\right)\)
\(m_{H_2O}=0.4\cdot18=7.2\left(g\right)\)
\(nMg=\dfrac{12}{24}=0,5\left(mol\right)\)
\(nH_2SO_4=\dfrac{29,4}{98}=0,3\left(mol\right)\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1 (mol)
0,3 0,3 0,3 0,3 (mol)
LTL : 0,5/1 > 0,3/1
=> Mg dư , H2SO4 đủ
\(VH_2=0,3.22,4=6,72\left(l\right)\)
m muối là mMgSO4
=> \(m\left(muối\right)=mMgSO_4=0,3.120=36\left(g\right)\)
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right);n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\\ a,Vì:\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCldư\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\ n_{HCl\left(dư\right)}=0,8-0,3.2=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,m_{MgCl_2}=0,3.95=28,5\left(g\right)\\ m_{HCl\left(dư\right)}=0,2.36,5=7,3\left(g\right)\)
a) \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
\(n_{HCl}=\dfrac{29.2}{36,5}=0,8\left(mol\right)\)
PTHH : 2Mg + 2HCl -> 2MgCl + H2
Xét tỉ lệ \(\dfrac{0,3}{2}< \dfrac{0,8}{2}\)
=> HCl dư
=> \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)
=> \(V_{MgCl}=0,15.22,4=3,36\left(l\right)\)
b) \(m_{H_2}=0,075.2=0,15\left(g\right)\\ m_{MgCl}=0,15.59,5=8,925\left(g\right)\)
n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)
n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)
\(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
bđ 0,1............0,5
pư 0,1............0,3..................0,1
spu 0 ................0,2................0,1
=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O
m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)
m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)
m dd = \(490+10,2=500,2g\)
% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)
% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)
\(n_{Fe_2O_3}=\dfrac{3.2}{160}=0.02\left(mol\right)\)
\(n_{HCl}=\dfrac{2.19}{36.5}=0.06\left(mol\right)\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(1...........6\)
\(0.02...........0.06\)
Lập tỉ lệ : \(\dfrac{0.02}{1}>\dfrac{0.06}{6}\Rightarrow Fe_2O_3dư\)
\(n_{Fe_2O_3\left(dư\right)}=0.02-\dfrac{0.06}{6}=0.01\left(mol\right)\)
\(m_{Fe_2O_3\left(dư\right)}=0.01\cdot160=1.6\left(g\right)\)
\(m_{FeCl_3}=0.02\cdot162.5=3.25\left(g\right)\)
\(m_{H_2O}=0.03\cdot18=0.54\left(g\right)\)
\(PTHH:Zn+2HCl->ZnCl_2+H_2\)
ap dung DLBTKL ta co
\(m_{Zn}+m_{HCl}=m_{ZnCl_2}+m_{H_2}\)
\(=>m_{H_2}=m_{Zn}+m_{HCl}-m_{ZnCl_2}\\ =>m_{H_2}=13+14,6-27,2\\ =>m_{H_2}=0,4\left(g\right)\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(m_{HCl}=36,5.15\%=5,475\left(g\right)\Rightarrow n_{HCl}=\dfrac{5,475}{36,5}=0,15\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,15}{2}\), ta được Mg dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\)
b, \(n_{Mg\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow n_{Mg\left(dư\right)}=0,1-0,075=0,025\left(mol\right)\)
\(\Rightarrow m_{Mg\left(dư\right)}=0,025.24=0,6\left(g\right)\)
c, - Cách 1:
\(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow m_{MgCl_2}=0,075.95=7,125\left(g\right)\)
- Cách 2:
Theo ĐLBT KL, có: mMg (pư) + mHCl = mMgCl2 + mH2
⇒ mMgCl2 = 2,4 - 0,6 + 5,475 - 0,075.2 = 7,125 (g)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
Ta có: \(n_{Na_2O}=\dfrac{24,8}{62}=0,4\left(mol\right)\)
\(n_{HNO_3}=\dfrac{50,4}{63}=0,8\left(mol\right)\)
PT: \(Na_2O+2HNO_3\rightarrow2NaNO_3+H_2O\)
____0,4_____0,8_________0,8 (mol)
→ Pư vừa đủ.
\(\Rightarrow m_{NaNO_3}=0,8.85=68\left(g\right)\)
Bạn tham khảo nhé!