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Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)
$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,15 0,3 0,15
\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)
\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)
\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)
b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,2
\(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)
\(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
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