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C → + O 2 A C O C O 2 → + F e O , t 0 B : C O 2 → + C a ( O H ) 2 K : C a C O 3 D : C a H C O 3 2 C F e F e O → + H C l H 2 E : F e C l 2 → + N a O H F : : F e O H 2 → t 0 , k k G : F e 2 O 3
⇒ Chọn A.
PTHH: \(CaO+2HNO_3\rightarrow Ca\left(NO_3\right)_2+H_2O\)
\(MgCO_3+2HNO_3\rightarrow Mg\left(NO_3\right)_2+CO_2\uparrow+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{MgCO_3}=n_{Mg\left(NO_3\right)_2}\) \(\Rightarrow n_{CaO}=\dfrac{18-0,1\cdot84}{56}=\dfrac{6}{35}\left(mol\right)=n_{Ca\left(NO_3\right)_2}\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,1\cdot84}{18}\cdot100\%\approx46,67\%\\\%m_{CaO}=53,33\%\end{matrix}\right.\)
Theo đề bài, ta có: \(m_{ddHNO_3}=500\cdot1,08=540\left(g\right)\) \(\Rightarrow\Sigma n_{HNO_3}=\dfrac{540\cdot12,6\%}{63}=1,08\left(mol\right)\)
Theo PTHH: \(n_{HNO_3\left(p.ứ\right)}=2n_{CaO}+2n_{MgCO_3}=\dfrac{19}{35}\left(mol\right)\) \(\Rightarrow n_{HNO_3\left(dư\right)}=\dfrac{94}{175}\left(mol\right)\)
Mặt khác: \(m_{CO_2}=0,1\cdot44=4,4\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.pư\right)}=m_A+m_{ddHNO_3}-m_{CO_2}=553,6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Mg\left(NO_3\right)_2}=\dfrac{0,1\cdot148}{553,6}\cdot100\%\approx2,67\%\\C\%_{Ca\left(NO_3\right)_2}=\dfrac{\dfrac{6}{35}\cdot164}{553,6}\cdot100\%\approx5,08\%\\C\%_{HNO_3\left(dư\right)}=\dfrac{\dfrac{19}{35}\cdot63}{553,6}\cdot100\%\approx6,18\%\end{matrix}\right.\)
\(n_{H_2SO_4}=\dfrac{19,6\%.500.1,12}{98}=1,12\left(mol\right)\\n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ MgO+H_2SO_4 \rightarrow MgSO_4+H_2O\\ CaCO_3+H_2SO_4\rightarrow CaSO_4+CO_2+H_2O\\ TH1:axit.hết\\ n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\\ \Rightarrow n_{MgO}=\dfrac{18-0,1.10}{40}=0,2\left(mol\right)\\ n_{H_2SO_4\left(p.ứ\right)}=0,2+0,1=0,3\left(mol\right)< 1,12\left(mol\right)\\ \Rightarrow LoạiTH1\\ TH2:axit.dư\\ \Rightarrow\left\{{}\begin{matrix}40a+100b=18\\b=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \Rightarrow\%m_{MgO}=\dfrac{0,2.40}{18}.100\approx44,444\%\Rightarrow\%m_{CaCO_3}\approx55,556\%\)
\(b,m_{ddB}=m_A+m_{ddH_2SO_4}-m_{CO_2}=18+500.1,12-0,1.44=573,6\left(g\right)\\ n_{H_2SO_4\left(dư\right)}=1,12-0,3=0,82\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,82.98}{573,6}.100\approx14,01\%\\ C\%_{ddCaCl_2}=\dfrac{0,1.111}{573,6}.100\approx1,935\%\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{573,6}.100\approx3,312\%\)
1. B
2. B
(Câu 2 cậu nên sửa lại câu hỏi nhé: Khối lượng dung dịch NaOH 10% ...)
Câu 1.
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1
\(V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\)
Chọn B.
Câu 2. \(n_{HCl}=0,2\cdot1=0,2mol\)
Để trung hòa: \(\Rightarrow n_{H^+}=n_{OH^-}=0,2\)
\(m_{NaOH}=0,2\cdot40=8\left(g\right)\)
\(m_{ddNaOH}=\dfrac{8}{10\%}\cdot100\%=80\left(g\right)\)
Chọn B.
Chọn A
Vì Ba( O H ) 2 dư do đó chỉ xảy ra phản ứng tạo kết tủa
PTHH: