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PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
Fe + 2HCl -> FeCl2 + H2
nFe = 5,6/56 = 0,1 mol
=>nH2 = 0,1 mol
=> VH2= 0,1*22,4= 2,24 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,1-->0,2------------------>0,1
=> \(\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,2.36,5}{15\%}=\dfrac{146}{3}\left(g\right)\\V_{H_2}=0,1.22,4=4,48\left(l\right)\end{matrix}\right.\)
\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 ( mol )
\(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8g\\m_{FeO}=12-8=4g\end{matrix}\right.\)
a)
FeO + H2 --to--> Fe + H2O
CuO + H2 --to--> Cu + H2O
b) \(n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1<--0,1<-----0,1
=> \(m_{FeO}=12-0,1.80=4\left(g\right)\)
=> \(n_{FeO}=\dfrac{4}{72}=\dfrac{1}{18}\left(mol\right)\)
FeO + H2 --to--> Fe + H2O
\(\dfrac{1}{18}\)-->\(\dfrac{1}{18}\)----->\(\dfrac{1}{18}\)
=> \(V_{H_2}=\left(0,1+\dfrac{1}{18}\right).22,4=\dfrac{784}{225}\left(l\right)\)
c) \(m_{Fe}=\dfrac{1}{18}.56=\dfrac{28}{9}\left(g\right)\)
d) \(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8\left(g\right)\\m_{FeO}=4\left(g\right)\end{matrix}\right.\)
`a)PTHH:`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,3` `0,6` `0,3` `0,3` `(mol)`
`n_[Fe]=[22,4]/56=0,4(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
Ta có:`[0,4]/1 > [0,6]/2`
`=>Fe` dư
`b)m_[FeCl_2]=0,3.127=38,1(g)`
`c)m_[Fe(dư)]=(0,4-0,3).56=5,6(g)`
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Xét: \(\dfrac{0,4}{1}>\dfrac{0,6}{2}\) ( mol )
0,3 0,6 0,3 ( mol )
\(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)
\(m_{Fe\left(dư\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\)
\(b,\) Đặt \(n_{Fe}=x(mol);n_{Al}=y(mol)\)
\(\Rightarrow 56x+27y=8,3(1)\)
Theo PTHH: \(x+1,5y=0,25(2)\)
\((1)(2)\Rightarrow x=y=0,1(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,1.56}{8,3}.100\%=67,47\%\\ \%_{Al}=100\%-67,47\%=32,53\%\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Ag}=y\left(mol\right)\end{matrix}\right.\Rightarrow27x+108y=4,2\left(1\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,05 0,15
\(\Rightarrow m_{Al}=0,1\cdot27=2,7g\)
\(\Rightarrow m_{Ag}=4,2-2,7=1,5g\)
a)\(\%m_{Al}=\dfrac{2,7}{4,2}\cdot100\%=64,28\%\)
\(\%m_{Ag}=100\%-64,28\%=35,72\%\)
b)\(m_{muối}=0,05\cdot342=17,1g\)
a) nFe=0,1(mol); nHCl=0,4(mol)
PTHH: Fe + 2 HCl -> FeCl2 + H2
Ta có: 0,1/1 < 0,4/2
=> Fe hết, HCl dư, tish theo nFe.
b) nH2=nFeCl2=Fe=0,1(mol)
=> V(H2,đktc)=0,1.22,4=2,24(l)
c) mFeCl2=127.0,1=12,7(g)
a) nFe=0,1(mol); nHCl=0,4(mol) PTHH: Fe + 2 HCl -> FeCl2 + H2 Ta có: 0,1/1 < 0,4/2 => Fe hết, HCl dư, tish theo nFe. b) nH2=nFeCl2=Fe=0,1(mol) => V(H2,đktc)=0,1.22,4=2,24(l) c) mFeCl2=127.0,1=12,7(g)
a.b.c.\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,1 0,15 ( mol )
\(V_{H_2}=0,15.22,4=3,36l\)
\(m_{AlCl_3}=0,1.133,5=13,35g\)
d.\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,15 0,1 ( mol )
\(m_{Fe}=0,1.56=5,6g\)
a) PTHH: Fe+2HCl→FeCl2+H2↑
Fe+2HCl→FeCl2+H2↑
b) Ta có: nH2=\(\dfrac{5,6}{22,4}\)=0,25(mol)=nFeCl2nH2=5,622,4=0,25(mol)=nFeCl2
⇒mFeCl2=0,25⋅127=31,75(g)⇒mFeCl2=0,25⋅127=31,75(g)
c) Theo PTHH: nH2=nFe=0,25molnH2=nFe=0,25mol ⇒mFe=0,25⋅56=14(g)
⇒mFe=0,25⋅56=14(g)
a) PTHH: Fe+2HCl→FeCl2+H2↑
b) Ta có: nH2=\(\dfrac{5,6}{22,4}\)
=0,25(mol)=nFeCl2nH2=5,622,4=0,25(mol)=nFeCl2
⇒mFeCl2=0,25⋅127=31,75(g)
c) Theo PTHH: nH2=nFe=0,25molnH2=nFe=0,25mol ⇒mFe=0,25⋅56=14(g)
⇒%mF