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a,\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: CuO + H2SO4 →CuSO4 + H2O
Mol: 0,25 0,25 0,25
\(m_{ddH_2SO_4}=\dfrac{0,25.98.100}{19,6}=125\left(g\right)\)
b,mdd sau pứ = 20+125 = 145 (g)
\(C\%_{ddCuSO_4}=\dfrac{0,25.160.100\%}{145}=27,59\%\)
\(Cu+H_2SO_4\rightarrow CuSO_4+H_2\)
0,3125 0,3125 0,3125 (mol)
a)\(n_{Cu}=\dfrac{20}{64}=0,3125\left(mol\right)\)
\(m_{H_2SO_4}=0,3125.98=30,625\left(g\right)\)
\(m_{ddH_2SO_4}=\dfrac{30,625}{19,6}.100=156,25\left(g\right)\)
b)\(m_{CuSO_4}=0,3125.160=50\left(g\right)\)
\(m_{ddCuSO_4}=20+156,25=176,25\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{50}{176,25}.100\approx28,37\%\)
\(n_{Fe2O3}=\dfrac{24}{160}=0,15\left(mol\right)\)
\(m_{ct}=\dfrac{19,6.300}{100}=58,8\left(g\right)\)
\(n_{H2SO4}=\dfrac{58,8}{98}=0,6\left(mol\right)\)
Pt : \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2|\)
1 3 1 3
0,15 0,6 0,15
a) Lập tỉ số so sánh : \(\dfrac{0,15}{1}< \dfrac{0,6}{3}\)
⇒ Fe2O3 phản ứng hết , H2SO4 dư
⇒ Tính toán dựa vào số mol của Fe2O3
\(n_{Fe2\left(SO4\right)3}=\dfrac{0,15.1}{1}=0,15\left(mol\right)\)
⇒ \(m_{Fe2\left(SO4\right)3}=0,15.400=60\left(g\right)\)
b) Dung dịch X sau phản ứng gồm : \(Fe_2\left(SO_4\right)_3\) va dung dịch \(H_2SO_4\) dư
\(n_{H2SO4\left(dư\right)}=0,6-\left(0,15.3\right)=0,15\left(mol\right)\)
⇒ \(m_{H2SO4\left(dư\right)}=0,15.98=14,7\left(g\right)\)
\(m_{ddspu}=24+300-324\left(g\right)\)
\(C_{Fe2\left(SO4\right)3}=\dfrac{60.100}{324}=18,52\)0/0
\(C_{H2SO4\left(dư\right)}=\dfrac{14,7.100}{324}=4,54\)0/0
Chúc bạn học tốt
a) Gọi \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
a--->a---------->a-------->a
Fe + H2SO4 --> FeSO4 + H2
b--->b----------->b------>b
=> \(m_{H_2SO_4}=98a+98b\left(g\right)\)
=> \(m_{ddH_2SO_4}=\dfrac{\left(98a+98b\right).100}{19,6}=500a+500b\left(g\right)\)
mdd sau pư = 24a + 56b + 500a + 500b - 2a - 2b = 522a + 554b (g)
Có: \(C\%_{FeSO_4}=\dfrac{152b}{522a+554b}.100\%=7,17\%\)
=> a = 3b
\(C\%_{MgSO_4}=\dfrac{120a}{522a+554b}.100\%=16,98\%\)
b)
Có: \(\left\{{}\begin{matrix}a=3b\\24a+56b=1,92\end{matrix}\right.\)
=> a = 0,045; b = 0,015
\(n_{CuSO_4}=0,1.1=0,1\left(mol\right)\)
PTHH: Mg + CuSO4 --> MgSO4 + Cu
0,045->0,045----->0,045
Fe + CuSO4 --> FeSO4 + Cu
0,015-->0,015----->0,015
=> \(\left\{{}\begin{matrix}n_{CuSO_4\left(dư\right)}=0,04\left(mol\right)\\n_{MgSO_4}=0,045\left(mol\right)\\n_{FeSO_4}=0,015\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(CuSO_4\left(dư\right)\right)}=\dfrac{0,04}{0,1}=0,4M\\C_{M\left(MgSO_4\right)}=\dfrac{0,045}{0,1}=0,45M\\C_{M\left(FeSO_4\right)}=\dfrac{0,015}{0,1}=0,15M\end{matrix}\right.\)
\(\left(a\right)Zn+2HCl\rightarrow ZnCl_2+H_2\\ DungdịchX:ZnCl_2, A:H_2,B:Ag\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{HCl}=2n_{H_2}=0,5\left(mol\right)\\ \Rightarrow x=m_{ddHCl}=\dfrac{0,5.36,5}{3,65}=500\left(g\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow y=m_{Ag}=27,05-0,2.65=14,05\left(g\right)\\ \left(b\right):m_{ddsaupu}=0,2.65+500-0,2.2=512,6\left(g\right)\\ TheoPT:n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnCl_2}=\dfrac{0,2.136}{512,5}.100=5,3\%\)
a) PTHH: CuO + H2SO4 → CuSO4 + H2O (1)
b) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
Theo PT1: \(n_{H_2SO_4}=n_{CuO}=0,2\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,2\times98=19,6\left(g\right)\)
\(\Rightarrow C\%_{ddH_2SO_4}=\dfrac{19,6}{400}\times100\%=4,9\%\)
c) Theo PT1: \(n_{CuSO_4}=n_{CuO}=0,2\left(mol\right)\)
\(\Rightarrow m_{CuSO_4}=0,2\times160=32\left(g\right)\)
\(\Sigma m_{dd}=16+400=416\left(g\right)\)
\(\Rightarrow C\%_{ddCuSO_4}=\dfrac{32}{416}\times100\%=7,69\%\)
d) CuSO4 + BaCl2 → BaSO4↓ + CuCl2 (2)
Theo PT2: \(n_{BaSO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,2\times233=46,6\left(g\right)\)
Vậy m=46,6
a) nCuO= \(\dfrac{20}{80}\)= 0,25 (mol)
CuO + H2SO4 \(\rightarrow\) CuSO4 + H2O
0,25____0,25_____0,25____0,25 ( mol )
mH2SO4= 0,25 . 98 = 24,5
=> mdd H2SO4= \(\dfrac{24,5}{19,6}.100\) = 125 (g)