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a, \(n_{HNO_3}=0,3.1=0,3\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,1.1=0,1\left(mol\right)\)
PT: \(2HNO_3+Ba\left(OH\right)_2\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{2}>\dfrac{0,1}{1}\), ta được HNO3 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{Ba\left(NO_3\right)_2}=n_{Ba\left(OH\right)_2}=0,1\left(mol\right)\\n_{HNO_3\left(pư\right)}=2n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\end{matrix}\right.\)
⇒ nHNO3 (dư) = 0,3 - 0,2 = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Ba\left(NO_3\right)_2}}=\dfrac{0,1}{0,3+0,1}=0,25\left(M\right)\\C_{M_{HNO_3\left(dư\right)}}=\dfrac{0,1}{0,3+0,1}=0,25\left(M\right)\end{matrix}\right.\)
b, Ta có: \(n_{Na_2CO_3}=0,25.0,5=0,125\left(mol\right)\)
PT: \(Na_2CO_3+2HNO_3\rightarrow2NaNO_3+CO_2+H_2O\)
______0,05______0,1_______________0,05 (mol)
⇒ VCO2 = 0,05.22,4 = 1,12 (l)
\(Na_2CO_3+Ba\left(NO_3\right)_2\rightarrow2NaNO_3+BaCO_{3\downarrow}\)
0,075________0,075_______________0,075 (mol)
⇒ mBaCO3 = 0,075.197 = 14,775 (g)
a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,15 0,3
Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H2 pứ hết,Fe dư
\(V_{H_2}=3,36\left(l\right)\) (đề cho)
b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd
\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `0,1` `(mol)`
`n_[HCl]=0,2.1=0,2(mol)`
`=>m_[Zn]=0,1.65=6,5(g)`
`b)m_[dd HCl]=1,1.200=220(g)`
`=>C%_[ZnCl_2]=[0,1.136]/[6,5+220-0,1.2].100~~6%`
\(a,n_{HCl}=0,2.1=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,1<--0,2------>0,1------->0,1
\(\rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(b,m_{ddHCl}=200.1,1=220\left(g\right)\)
\(\rightarrow m_{dd}=220+6,5-0,1.2=226,3\left(g\right)\\ \rightarrow C\%_{ZnCl_2}=\dfrac{0,1.136}{226,3}.100\%=6\%\)
a)
\(n_{CaO}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: CaO + H2O --> Ca(OH)2
0,15----------->0,15
=> mCa(OH)2 = 0,15.74 = 11,1 (g)
b) \(C_M=\dfrac{0,15}{0,5}=0,3M\)
c)
PTHH: 2Ca + O2 --to--> 2CaO
0,075<----0,15
=> VO2 = 0,075.24,79 = 1,85925 (l)
\(a,n_{CaO}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: CaO + H2O ---> Ca(OH)2
0,15-------------->0,15
=> mCa(OH)2 = 0,15.74 = 11,1 (g)
b, \(C_{M\left(Ca\left(OH\right)_2\right)}=\dfrac{0,15}{0,5}=0,3M\)
c, PTHH: 2Ca + O2 --to--> 2CaO
0,075<------0,15
=> VO2 = 0,075.24,79 = 1,85925 (l)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CaCO_3}=n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\)
nCa(OH)2 = 0.15 mol
nHCl = 0.2 mol
Ca(OH)2 + 2HCl --> CaCl2 + 2H2O
Bđ: __0.15_____0.2
Pư: __0.1______0.2______0.1
Kt: __0.05______0_______0.1
CM Ca(OH)2 dư = 0.05/0.5 = 0.1M
CM CaCl2 = 0.1/(0.2 + 0.3) = 0.2M
Ca(OH)2 + CO2 --> CaCO3 + H2O
0.05_______________0.05
mCaCO3 = 0.05*100 = 5 g