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\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,1 0,2
a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)
1 1 1 1
0,1 0,1
\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)
c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)
1 2 1 1
0,05 0,1
\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
Ủa fen ơi, nFeCl2 sinh ra là 0,1 mol rồi còn tác dụng đủ sao được với Ba(OH)2 0,05 mol fen=)
\(n_{Fe}=a;n_{Cu}=b\\a. Fe+2HCl->FeCl_2+H_2\\ 2HCl+Ba\left(OH\right)_2->BaCl_2+2H_2O\\ b.m_{Fe}=56\cdot\dfrac{2,24}{22,4}=5,6g\\ \%m_{Fe}=\dfrac{5,6}{8,8}.100\%=63,64g\\ \%m_{Cu}=36,36\%\\ c.\sum n_{HCl}=0,2+2.0,1.0,5=0,3mol\\ x=\dfrac{0,3}{0,3}=1\left(M\right)\)
\(n_{Na_2CO_3}=\dfrac{200.0,159}{106}=0,3mol\\ n_{BaCl_2}=\dfrac{200.0,208}{208}=0,2mol\\ a.Na_2CO_3+BaCl_2->2NaCl+BaCO_3\\ n_{Na_2CO_3}:1>n_{BaCl_2}:1\\ m_B=197.0,2=39,4g\\ Na_2CO_3+2HCl->2NaCl+H_2O+CO_2\\ V=\dfrac{2.0,1}{1}=0,2\left(L\right)=200\left(mL\right)\\ b.m_A=200+200-39,4=360,6g\\ C\%_{Na_2CO_3du}=\dfrac{106.0,1}{360,6}.100\%=2,94\%\\ C\%_{NaCl}=\dfrac{58,5.0,4}{360,6}.100\%=6,49\%\)
a)
\(Na_2CO_3+BaCl_2\rightarrow BaCO_3+2NaCl\)
0,2 <---------- 0,2 ------> 0,2 -----> 0,4
\(n_{Na_2CO_3}=\dfrac{200.15,9\%}{100\%}:106=0,3\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{200.20,8\%}{100\%}:208=0,2\left(mol\right)\)
Do \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) nên \(Na_2CO_3\) dư sau phản ứng.
Dung dịch A: \(n_{Na_2CO_3}=0,3-0,2=0,1\left(mol\right);n_{NaCl}:0,4\left(mol\right)\)
Kết tủa B: \(BaCO_3\)
\(m_B=m_{BaCO_3}=0,2.197=39,4\left(g\right)\)
Dung dịch A td với HCl:
\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
0,1 ---------> 0,2
\(V=V_{HCl}=\dfrac{0,2}{1}=0,2\left(l\right)\)
b)
\(m_{dd}=m_{dd.Na_2CO_3}+m_{dd.BaCl_2}-m_{BaCO_3}=200+200-39,4=360,6\left(g\right)\)
\(C\%_{Na_2CO_3}=\dfrac{0,1.106.100\%}{360,6}=2,94\%\)
\(C\%_{NaCl}=\dfrac{0,4.58,5.100\%}{360,6}=6,49\%\)
\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{Zn}=\dfrac{4,55}{65}=0,07\left(mol\right)\\ n_{H_2}=n_{Zn}=0,07\left(mol\right)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568\left(l\right)\\ b.n_{HCl}=2n_{Zn}=0,14\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,14}{0,2}=0,7M\\ c.n_{ZnCl_2}=n_{Zn}=0,07\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52\left(g\right)\)
\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)
\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)
mNa2CO3 = 10.6 g
nNa2CO3 = 0.1 mol
mHCl = 100*7.3/100= 73g
nHCl = 2 mol
Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
Bđ: 0.1________2
Pư : 0.1________0.2_____0.2____0.1
Kt : 0_________1.8______0.2____0.1
VCO2 = 2.24 l
mCO2 = 4.4g
mHCl dư = 65.7 g
mNaCl = 11.7 g
mdd sau phản ứng = 200 + 100 - 4.4 = 295.6 g
C%HCl dư = 22.22%
C%NaCl = 3.95%
OH- + H+ --> H2O
1.8___1.8
CM NaOH = 1.8/0.1 = 18M