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\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ a,V_{H_2\left(Đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,m_{ZnCl_2}=136.0,2=27,2\left(g\right)\\ c,n_{HCl}=0,2.2=0,4\left(mol\right)\\ C\%_{ddHCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)
\(n_{Zn}=\dfrac{19.5}{65}=0.3\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.3........................0.3..........0.3\)
\(m_{ZnSO_4}=0.3\cdot161=48.3\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(n_{CuO}=\dfrac{16}{80}=0.2\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(0.2..........0.3\)
\(LTL:\dfrac{0.2}{1}< \dfrac{0.3}{1}\Rightarrow H_2dư\)
\(m_{H_2\left(dư\right)}=\left(0.3-0.2\right)\cdot2=0.2\left(g\right)\)
a) $Zn + H_2SO_4 → ZnSO_4 + H_2$
b) n ZnSO4 = n Zn = 19,5/65 = 0,3(mol)
=> m ZnSO4 = 0,3.161 = 48,3(gam)
c) n H2 = n Zn = 0,3(mol)
V H2 = 0,3.22,4 = 6,72 lít
c)
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
n CuO = 16/80 = 0,2(mol) < n H2 = 0,3 nên H2 dư
n H2 pư = n CuO = 0,2(mol)
=> m H2 dư = (0,3 - 0,2).2 = 0,2(gam)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\\
m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
a)
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
n ZnSO4 = n Zn = 19,5/65 = 0,3(mol)
m ZnSO4 = 0,3.161 = 48,3(gam)
b)
n H2 = n Zn = 0,3(mol)
V H2 = 0,3.22,4 = 6,72(lít)
c) $CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
n CuO / 1 = 16/80 = 0,2 < n H2 / 1 = 0,3 nên H2 dư
n H2 pư = n CuO = 0,2(mol)
m H2 dư = (0,3 - 0,2).2 = 0,2(gam)
PTHH: Zn + H2SO4 (loãng) -> ZnSO4 + H2
Ta có:\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Theo PTHH và đề bài, ta có:
\(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,3\left(mol\right)\)
a) Khối lượng ZnSO4 thu đc:
\(m_{ZnSO_4}=0,3.161=48,3\left(g\right)\)
b) Thể tích khí H2 thu được (đktc):
\(V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\)
c) PTHH: H2 + CuO -to-> Cu + H2O
Ta có:
\(n_{H_2}=0,3\left(mol\right)\)
\(n_{CuO}=0,2\left(mol\right)\)
Theo PTHH và đề bài, ta có:
\(\dfrac{0,3}{1}< \dfrac{0,2}{1}\)
=> H2 dư, CuO hết nên tính theo nCuO
Theo PTHH và đb , ta có:
\(n_{H_2}\)(phản ứng) \(=n_{CuO}=0,2mol\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(a,V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(b,m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
\(c,m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{ddMgCl_2}=4,8+146-\left(0,2.2\right)=150,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{150,4}.100\%\approx12,63\%\)
2.
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
\(2K+2H_2O\rightarrow2KOH+H_2\uparrow\)
0,2 0,2 0,1
\(m_{KOH}=0,2.56=11,2\left(g\right)\)
\(m_{ddKOH}=7,8+100-\left(0,1.2\right)=107,6\left(g\right)\)
\(C\%=\dfrac{11,2}{107,6}.100\%\approx10,4\%\)
Coi như p/ứ vừa đủ
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3 \left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}=n_{H_2}\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4}=\dfrac{0,3\cdot98}{200}=14,7\%\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\m_{ZnSO_4}=0,3\cdot161=48,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Zn}+m_{ddH_2SO_4}-m_{H_2}=218,9\left(g\right)\)
\(\Rightarrow C\%_{ZnSO_4}=\dfrac{48,3}{218,9}\cdot100\%\approx22,06\%\)