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a, \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,125 0,25
b, \(C_{M_{ddNaOH}}=\dfrac{0,25}{0,25}=1M\)
c,
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,25 0,125
\(m_{ddH_2SO_4}=\dfrac{0,125.98.100}{20}=61,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,14}=53,728\left(ml\right)\)
1. \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,25 0,5
\(C_{M_{ddNaOH}}=\dfrac{0,5}{0,5}=1M\)
2.
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,5 0,25
\(m_{ddH_2SO_4}=\dfrac{0,25.98.100}{20}=122,5\left(g\right)\)
\(V_{ddH_2SO_4}=\dfrac{122,5}{1,14}=107,456\left(ml\right)\)
\(n_{Na2O}=\dfrac{m_{Na2O}}{M_{Na2O}}=0,25\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,25 mol - 0,25 mol - 0,5 mol
a) \(C_{M_{NaOH}}=\dfrac{n_{NaOH}}{V_{NaOH}}=1\left(M\right)\)
b) \(H_2SO_4+2NaOH\rightarrow Na_2SO4+2H_2O\)
0,25 mol - 0,5 mol - 0,25 mol - 0,5 mol
\(m_{ctH2SO4}=n_{H2SO4}.M_{H2SO4}=24,5\left(g\right)\)
\(C_{\%_{H2SO4}}=\dfrac{m_{ctH2SO4}}{m_{ddH2SO4}}.100\%\)
\(\Rightarrow m_{ddH2SO4}=\dfrac{m_{ctH2SO4}.100\%}{C_{\%_{H2SO4}}}=122,5\left(g\right)\)
\(D_{H2SO4}=\dfrac{m_{ddH2SO4}}{V_{H2SO4}}\Rightarrow V_{H2SO4}=\dfrac{m_{ddH2SO4}}{D_{H2SO4}}\approx107,46\left(ml\right)\)
\(a,PTHH:Na_2O+H_2O\rightarrow2NaOH\\ \Rightarrow n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{37,2}{62}=0,6\cdot2=1,2\left(mol\right)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{1,2}{0,5}=2,4M\\ b,PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{58,8\cdot100\%}{20\%}=294\left(g\right)\\ \Rightarrow V_{dd}=\dfrac{294}{1,14}\approx257,9\left(ml\right)\)
1 , \(n_{Na}=\frac{4,6}{23}=0,2\left(mol\right)\)
\(m_{HCl}=200.2,92\%=5,84\left(mol\right)\) => \(n_{HCl}=\frac{5,84}{36,5}=0,16\left(mol\right)\)
\(2Na+2HCl->2NaCl+H_2\left(1\right)\)
vì \(\frac{0,2}{2}>\frac{0,16}{2}\) => Na dư , HCl hết
dung dịch thu được là dung dịch NaCl
theo (1) \(n_{NaCl}=n_{HCl}=0,16\left(mol\right)\) => \(m_{NaCl}=0,16.58,5=9,36\left(g\right)\)
\(n_{H_2}=\frac{1}{2}n_{HCl}=0,08\left(mol\right)\)
khối lượng dung dịch sau phản ứng là
4,6+200-0,08.2=204,44(g)
\(C_{\%\left(NaCl\right)}=\frac{9,36}{204,44}.100\%\approx4,58\%\)
Gọi $n_{Na_2O} = 2a(mol) \Rightarrow n_{K_2O} = a(mol)$
$\Rightarrow 2a.62 + 94a = 21,8 \Rightarrow a = 0,1(mol)$
$Na_2O + H_2O \to 2NaOH$
$K_2O + H_2O \to 2KOH$
$n_{NaOH} = 2n_{Na_2O} = 0,4(mol)$
$n_{KOH} = 2n_{K_2O} = 0,2(mol)$
$C_{M_{NaOH}} = \dfrac{0,4}{0,5} = 0,8M$
$C_{M_{KOH}} = \dfrac{0,2}{0,5} = 0,4M$
$m_{dd} = D.V = 1,04.500 = 520(gam)$
$C\%_{NaOH} = \dfrac{0,4.40}{520}.100\% = 3,1\%$
$C\%_{KOH} = \dfrac{0,2.56}{520}.100\% = 2,15\%$
\(n_{K2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,2 0,4
\(n_{KOH}=\dfrac{0.2.2}{1}=0,4\left(mol\right)\)
\(m_{KOH}=0,4.56=22,4\left(g\right)\)
\(m_{ddKOH}=1,045.200=209\left(g\right)\)
\(C_{ddKOH}=\dfrac{22,4.100}{209}=10,72\)0/0
⇒ Chọn câu : B
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