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\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
a, Cu không tác dụng với dd HCl.
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(\Rightarrow m_{Cu}=19,4-13=6,4\left(g\right)\)
c, Ta có: \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{13}{19,4}.100\%\approx67,01\%\\\%m_{Cu}\approx32,99\%\end{matrix}\right.\)
Bạn tham khảo nhé!
`a)Fe + 2HCl -> FeCl_2 + H_2 \uparrow`
`0,1` `0,1` `(mol)`
`Cu + HCl -xx->`
`b)n_[H_2]=[2,479]/[22,4]=0,1 (mol)`
`m_[Fe]=0,1.56=5,6(g)`
`=>m_[Cu]=10-5,6=4,4(g)`
`c)%m_[Fe]=[5,6]/10 .100=56%`
`%m_[Cu]=100-56=44%`
`d)` Dung dịch sau phản ứng có làm đổi màu quỳ tím. Vì: `HCl` dư nên sau phản ứng quỳ tím đổi màu đỏ.
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)
2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
Gọi số mol Na, Zn là a, b
=> 23a + 65b = 14,3
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
- Nếu Zn tan hết
PTHH: 2Na + 2H2O --> 2NaOH + H2
______a-------------------->a---->0,5a
2NaOH + Zn --> Na2ZnO2 + H2
__2b<----b-------------------->b
=> \(\left\{{}\begin{matrix}2b\le a\\0,5a+b=14,3\end{matrix}\right.\) => Loại
=> Zn không tan hết => NaOH hết
PTHH: 2Na + 2H2O --> 2NaOH + H2
______a------------------->a---->0,5a
2NaOH + Zn --> Na2ZnO2 + H2
_a--------------------------->0,5a
=> 0,5a + 0,5a = 0,1
=> a = 0,1
=> mNa = 0,1.23 = 2,3 (g)
=> mZn = 14,3 - 2,3 = 12(g)
a)
\(n_{H_2\left(1\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2 (1)
0,6<----------------------0,3
=> mNa = 0,6.23 = 13,8 (g)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,1<-0,2
=> mFe = 0,1.56 = 5,6 (g)
mCu = 10 (g)
\(\left\{{}\begin{matrix}\%Na=\dfrac{13,8}{13,8+5,6+10}.100\%=46,94\%\\\%Fe=\dfrac{5,6}{13,8+5,6+10}.100\%=19,05\%\\\%Cu=\dfrac{10}{13,8+5,6+10}.100\%=34,01\%\end{matrix}\right.\)
b)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,3}{y}\)<--0,3
=> \(M_{Fe_xO_y}=\dfrac{17,4}{\dfrac{0,3}{y}}=58y\left(g/mol\right)\)
=> 56x = 42y
=> \(\dfrac{x}{y}=\dfrac{3}{4}\) => CTHH: Fe3O4
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(\left\{{}\begin{matrix}n_{Na}=x\left(mol\right)\\n_{Ba}=y\left(mol\right)\end{matrix}\right.\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(\Rightarrow\left\{{}\begin{matrix}0,5x+y=0,2\\23x+137y=18,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{Na}=\dfrac{0,2\cdot23}{18,3}\cdot100\%=25,14\%\)
Chọn D