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\(n_{H_2SO_4}=\dfrac{98.5\%}{98}=0,05\left(mol\right)\\ PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=n_{H_2SO_4}=0,05\left(mol\right)\\ a,m_{CuO}=0,05.80=4\left(g\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ m_{ddCuSO_4}=98+4=102\left(g\right)\\ C\%_{ddCuSO_4}=\dfrac{8}{102}.100\approx7,843\%\)
nHCl= (7,3%.250)/100=0,5(mol)
nCuO=0,05(mol)
a) PTHH: CuO +2 HCl -> CuCl2 + H2O
Ta có: 0,5/2 > 0,05/1
=> HCl dư, CuO hết => tính theo nCuO
b) nCuCl2=nCuO=0,05(mol) => mCuCl2= 135. 0,05= 6,75(g)
c) nHCl(dư)=0,5-0,05.2=0,4(mol) => mHCl(dư)=0,4.36,5=14,6(g)
mddsau=250+4= 254(g)
=>C%ddCuCl2= (6,75/254).100=2,657%
C%ddHCl(dư)= (14,6/254).100=5,748%
\(a.n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\ a.CuO+2HCl\rightarrow CuCl_2+H_2O\\ 0,05.......0,1........0,05.......0,05\left(mol\right)\\ b.m_{CuCl_2}=135.0,05=6,75\left(g\right)\\ b.C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
Câu 3 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
a) Pt : \(CuO+2HCl\rightarrow CuCl_2+H_2O|\)
1 2 1 1
0,05 0,1 0,05
b) \(n_{CuCl2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
⇒ \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(n_{HCl}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddHCl}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
Chúc bạn học tốt
\(a,m_{Na_2CO_3}=\dfrac{500.20}{100}=100\left(g\right)\\ \rightarrow n_{Na_2CO_3}=\dfrac{100}{106}=\dfrac{50}{53}\left(mol\right)\)
PTHH: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2\uparrow+H_2O\)
\(\dfrac{50}{53}\)------->\(\dfrac{100}{53}\)--------------->\(\dfrac{100}{53}\)-------------->\(\dfrac{50}{53}\)
\(b,m_{axit}=\dfrac{100}{53}.60=\dfrac{6000}{53}\left(g\right)\\ c,m_{dd}=500+400-\dfrac{50}{53}.44=\dfrac{45500}{53}\left(g\right)\\ m_{CH_3COONa}=\dfrac{100}{53}.82=\dfrac{8200}{53}\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{\dfrac{8200}{23}}{\dfrac{45500}{23}}.100\%=18,02\%\)
\(n_{HCl}=2\cdot0,1=0,2\left(mol\right)\\ PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow n_{CuCl_2}=n_{CuO}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{CuCl_2}=0,1\cdot135=13,5\left(g\right)\\m_{CuO}=0,1\cdot80=8\left(g\right)\end{matrix}\right.\)
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nCuO=0.2(mol)
CuO+2HCl->CuCl2+H2O
0.2 0.4 0.2
m muối=0.2*(64+71)=27(g)
m HCl=14.6(g)
CM=0.4/0.2=2(M)