Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)
Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)
c, Ta có: m dd HCl = 1,05.500 = 525 (g)
m dd sau pư = mhh + m dd HCl - mH2 = 541,2 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)
a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)
\(n_{H_2}=0,4\left(mol\right)\)
Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)
=> x=0,2 ; y=0,2
\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)
b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)
c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)
=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
2 kim loại gồm Fe, Cu
\(n_{Al}=a;n_{Fe\left(pư\right)}=b;n_{Fe\left(dư\right)}=c\\ 27a+56\left(b+c\right)=8,3\\ n_{Cu}=0,2.1,05=0,21=1,5a+b\\ m_X=56c+64.0,21=15,68\\ a=0,1;b=0,06;c=0,04\\ \%m_{Al}=\dfrac{27a}{8,3}.100\%=32,53\%\\ \%m_{Fe}=67,47\%\)
nH2= \(\dfrac{0,896}{22,4}\) = 0,04(mol)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2\(\uparrow\)
a \(\rightarrow\) a (mol)
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2\(\uparrow\) (ai dạy Al hóa trị II thế =.=)
b \(\rightarrow\) 1,5b (mol)
Gọi a,b lần lượt là số mol của Mg và Al
Theo đầu bài, ta có: \(\left\{{}\begin{matrix}24a+27b=0.78\\a+1,5b=0,04\end{matrix}\right.\) \(\Rightarrow\)\(\left\{{}\begin{matrix}a=0,01\\b=0,02\end{matrix}\right.\)
=> mMg= 0,01.24 = 0,24(g)
=> mAl = 0,78 - 0,24 = 0,54(g)
a) PTHH : \(2Al+6HCl-->2AlCl_3+3H_2\) (1)
\(Fe+2HCl-->FeCl_2+H_2\) (2)
\(H_2+CuO-t^o->Cu+H_2O\) (3)
b) Ta có : \(m_{CR\left(giảm\right)}=m_{O\left(lay.di\right)}\)
=> \(m_{O\left(lay.di\right)}=32-26,88=5,12\left(g\right)\)
=> \(n_{O\left(lay.di\right)}=\frac{5,12}{16}=0,32\left(mol\right)\)
Theo pthh (3) : \(n_{H_2\left(pứ\right)}=n_{O\left(lay.di\right)}=0,32\left(mol\right)\)
=> \(tổng.n_{H_2}=\frac{0,32}{80}\cdot100=0,4\left(mol\right)\)
Đặt \(\hept{\begin{cases}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{cases}}\) => \(27a+56b=11\left(I\right)\)
Theo pthh (1) và (2) : \(n_{H_2\left(1\right)}=\frac{3}{2}n_{Al}=\frac{3}{2}a\left(mol\right)\)
\(n_{H_2\left(2\right)}=n_{Fe}=b\left(mol\right)\)
=> \(\frac{3}{2}a+b=0,4\left(II\right)\)
Từ (I) và (II) => \(\hept{\begin{cases}a=0,2\\b=0,1\end{cases}}\)
=> \(\hept{\begin{cases}m_{Al}=27\cdot0,2=5,4\left(g\right)\\m_{Fe}=56\cdot0,1=5,6\left(g\right)\end{cases}}\)
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{HCl}=0,1.1,2=0,12\left(mol\right)\\ n_{H_2}=0,05\left(mol\right)\)
PTHH:
2Al + 6HCl ---> 2AlCl3 + 3H2
a 3a a 1,5a
Fe + 2HCl ---> FeCl2 + H2
b 2b b b
Hệ pt \(\left\{{}\begin{matrix}27a+56b=1,66\\1,5a+b=0,05\end{matrix}\right.\Leftrightarrow a=b=0,02\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al}=0,02.27=0,54\left(g\right)\\m_{Fe}=0,02.56=1,12\left(g\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,02}{0,1}=0,2M\\C_{M\left(FeCl_2\right)}=\dfrac{0,02}{0,1}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{0,12-0,02.3-0,02.2}{0,1}=0,2M\end{matrix}\right.\)