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Bài 3 :
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)
2 3 1 3
0,1 0,15 0,05 0,15
a) \(n_{H2}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
\(m_{H2}=0,15.2=0,3\left(g\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
⇒ \(m=0,15.98=14,7\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{14,7.100}{200}=7,35\)0/0
c) \(n_{Al2\left(SO4\right)3}=\dfrac{0,15.1}{3}=0,05\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,05.342=17,1\left(g\right)\)
\(m_{ddspu}=2,7+200-0,3=302,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{302,4}=5,65\)0/0
Chúc bạn học tốt
Mình xin lỗi bạn nhé , bạn sửa lại giúp mình :
\(m_{ddspu}=2,7+200-0,3=202,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{202,4}=8,45\)0/0
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05 0,15
\(m_{H_2}=0,15.2=0,3\left(g\right)\)
\(V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(m_{ddH_2SO_4}=\dfrac{0,15.98.100\%}{200}=7,35\%\)
c, mdd sau pứ = 2,7 + 200 - 0,3 = 202,4 (g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{202,4}=8,45\%\)
a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)
\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na2CO3 hết, CH3COOH dư
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15-------->0,3-------------->0,3------->0,15
=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)
b) mdd sau pư = 120 + 53 - 0,15.44 = 166,4 (g)
=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
a) Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)
1 1 1 1
0,2 0,2 0,2
b) \(n_{H2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{H2SO4}=0,2.98=19,6\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{19,6.100}{200}=9,8\)0/0
c) \(n_{CuSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CuSO4}=0,2.160=32\left(g\right)\)
\(m_{ddspu}=16+200=216\left(g\right)\)
\(C_{CuSO4}=\dfrac{32.100}{216}=14,81\)0/0
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot9,8\%}{98}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\) \(\Rightarrow\) Fe2O3 còn dư, tính theo axit
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\\m_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\cdot160\approx5,3\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+200-5,3}\cdot100\%\approx18,98\%\)