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\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)
Nồng độ mol/lít các ion trong dd A:
\(\left[OH^-\left(dư\right)\right]=0,06\left(M\right)\left(nt\right)\\\left[Cl^-\right]=2.\left[BaCl_2\right]=2.\left(\dfrac{0,015}{0,5}\right)=0,06\left(M\right)\\ \left[Ba^{2+}\right]=0,03+ 0,03=0,06\left(M\right)\)
Câu 3 :
\(pH=-log\left[H^+\right]=-log\left(0.1\right)=1\)
Câu 4 :
Chứa các ion : H+ , Cl-
Câu 5 :
\(n_{NaOH}=n_{HCl}=0.02\cdot0.1=0.002\left(mol\right)\)
\(\Rightarrow x=\dfrac{0.002}{0.01}=0.2\left(M\right)\)
Câu 1 :
Bảo toàn điện tích :
\(n_{SO_4^{2-}}=\dfrac{0.2\cdot2+0.1-0.05}{2}=0.225\left(mol\right)\)
\(m_{Muối}=0.2\cdot64+0.1\cdot39+0.05\cdot35.5+0.225\cdot96=40.075\left(g\right)\)
Câu 2 :
\(\left[Na^+\right]=\dfrac{0.15\cdot0.5\cdot2+0.05\cdot1}{0.15+0.05}=1\left(M\right)\)
a, \(\left[Ca^{2+}\right]=\dfrac{0,15.0,5}{0,15+0,05}=0,375M\)
\(\left[Na^+\right]=\dfrac{0,05.2}{0,15+0,05}=0,5M\)
\(\left[Cl^-\right]=\dfrac{0,15.2.0,5+0,05.2}{0,15+0,05}=1,25M\)
\(n_{NaCl}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{AgNO_3}=0.15\cdot0.1=0.015\left(mol\right)\)
\(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\)
\(0.01..........0.01...............0.01\)
Dung dịch : 0.01 (mol) NaNO3 , 0.005 (mol) AgNO3
\(\left[Na^+\right]=\dfrac{0.01}{0.1+0.15}=0.04\left(M\right)\)
\(\left[Ag^+\right]=\dfrac{0.005}{0.25}=0.02\left(M\right)\)
\(\left[NO_3^-\right]=\dfrac{0.01+0.005}{0.25}=0.06\left(M\right)\)
a, \(n_{H^+}=n_{OH^-}=9.10^{-3}\left(mol\right)\Rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{\dfrac{9.10^{-3}}{2}}{0,05}=0,09M\)
b, \(\left[SO_4^{2-}\right]=\dfrac{4,5.10^{-3}}{0,05+0,15}=0,6M\)
\(\left[Na^+\right]=\dfrac{0,15.0,06}{0,05+0,15}=0,045M\)
\(\left[H^+\right]=\left[OH^-\right]=\dfrac{9.10^{-3}}{0,05+0,15}=0,045M\)
\(n_{Cl^-}=n_{KCl}+2n_{CaCl_2}=0,15.0,1+0,15.0,1.2=0,045\left(mol\right)\\ \Rightarrow\left[Cl^-\right]=\dfrac{0,045}{0,15}=0,3M\)