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a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,04<--0,04
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)
b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,56----------->0,56
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,04----------->0,08
\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Giả sử: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{1,344}{22,4}=0,06\left(1\right)\)
Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y\left(mol\right)\)
⇒ x + 2y = 0,1 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,02}{0,06}.100\%\approx33,33\%\\\%\text{ }V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Ta có: 1/2 hỗn hợp khí gồm: 0,01 mol C2H4 và 0,02 mol C2H2.
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=2n_{C_2H_4}+2n_{C_2H_2}=0,06\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,06\left(mol\right)\)
\(\Rightarrow m_{cr}=m_{CaCO_3}=0,06.100=6\left(g\right)\)
Bạn tham khảo nhé!
C2H2+2Br2->C2H2Br4
x-----------2x
C2H4+Br2->C2H4Br2
y-----------2y
n Br2=0,8 mol
\(\left\{{}\begin{matrix}x+y=0,6\\2x+y=0,8\end{matrix}\right.\)
=>x=0,2 ,y=0,4 mol
=>%VC2H2=\(\dfrac{0,2.22,4}{13,44}100\)=33,33%
=>%C2H4=66,67%
C2H4+3O2-tO>2CO2+2H2O
C2H2+5\2O2-to>2CO2+H2O
=>Vkk=1,7.22,4.5=190,4l
Bài 3
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)
Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{0,56}{22,4}=0,025\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = 0,035 (2)
(1)(2) => a = 0,015 (mol); b = 0,01 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,015}{0,025}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,01}{0,025}.100\%=40\%\end{matrix}\right.\)
Bài 4:
a)
CH4 + 2O2 --to--> CO2 + 2H2O
2H2 + O2 --to--> 2H2O
b)
Gọi số mol CH4, H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a-------------------->a--->2a
2H2 + O2 --to--> 2H2O
b--------------->b
=> \(2a+b=\dfrac{16,2}{18}=0,9\) (2)
(1)(2) => a = 0,4 (mol); b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,4}{0,5}.100\%=80\%\\\%V_{H_2}=\dfrac{0,1}{0,5}.100\%=20\%\end{matrix}\right.\)
c)
VCO2 = 0,4.22,4 = 8,96 (l)
\(a) C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ b) n_{C_2H_4} = a(mol) ; n_{C_2H_2} = b(mol)\\ n_X = a + b = \dfrac{0,56}{22,4} = 0,025(mol)\\ n_{Br_2} = a + 2b = \dfrac{5,6}{160} =0,035(mol)\\ \Rightarrow a = 0,015 ; b = 0,01\\ \%V_{C_2H_4} = \dfrac{0,015}{0,025}.100\% = 60\%\\ \%V_{C_2H_2} = 100\% -60\% = 40\%\)
\(c) C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ 2C_2H_2 + 5O_2 \xrightarrow{t^o} 4CO_2 + 2H_2O\\ n_{O_2} = 3n_{C_2H_4} + \dfrac{5}{2}n_{C_2H_2} = 0,07(mol)\\ V_{O_2} = 0,07.22,4 = 1,568(lít)\)
a)
$C_2H_4 + Br_2 \to C_2H_4Br_2$
$n_{C_2H_4} = n_{Br_2} = \dfrac{24}{160} = 0,15(mol)$
$n_X = \dfrac[7,84}{22,4} = 0,35(mol)$
$\Rightarrow n_{CH_4} = 0,35 - 0,15 = 0,2(mol)$
$CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
$C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O$
$n_{O_2} = 2n_{CH_4} + 3n_{C_2H_4} = 0,85(mol)$
$V_{O_2} = 0,85.22,4 = 19,04(lít)$
$V_{không\ khí} = V_{O_2} : 20\% = 95,2(lít)$
b)
$M_X = \dfrac{0,2.16 + 0,15.28}{0,35} = 21,14(g/mol)$
$d_{X/không\ khí} = \dfrac{21,14}{29} = 0,73$
a.\(n_{Br_2}=\dfrac{48}{160}=0,3mol\)
\(n_{hh}=\dfrac{7,84}{22,4}=0,35mol\)
\(C_2B_2+2Br_2\rightarrow C_2H_2Br_4\)
0,15 0,3 ( mol )
\(\%V_{C_2H_2}=\dfrac{0,15}{0,35},100=42,85\%\)
\(\%V_{CH_4}=100\%-42,85\%=57,15\%\)
b.\(n_{CH_4}=0,35-0,15=0,2mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,4 ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,15 0,15 ( mol )
\(m_{H_2O}=\left(0,4+0,15\right).18=9,9g\)
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
=> a + 2b = 0,1 (2)
(1)(2) => a = 0,05 (mol); b = 0,025 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)
c)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,025-->0,0625
=> VO2 = (0,15 + 0,0625).22,4 = 4,76 (l)
a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)
\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)
c.
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,025 0,0625 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,15 ( mol )
\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)
a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\) => \(a+b=\dfrac{13,44}{22,4}=0,6\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a--->a
C2H2 + 2Br2 --> C2H2Br4
b--->2b
=> \(a+2b=0,8.1=0,8\) (2)
(1)(2) => a = 0,4 (mol); b = 0,2 (mol)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,4--->1,2
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,2---->0,5
=> \(V_{O_2}=\left(1,2+0,5\right).22,4=38,08\left(l\right)\)
=> Vkk = 38,08 : 20% = 190,4 (l)