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\(nCuO=\dfrac{8}{80}=0,1\left(mol\right)\)
\(nH_2SO_4=\dfrac{19,6}{98}=0,2\left(mol\right)\)
\(LTL:\dfrac{0,1}{1}< \dfrac{0,2}{1}\)
=> CuO pứ đủ , H2SO4 dư
CuO+H2SO4 -> CuSO4+H2O
0,1 0,1 0,1 0,1
\(nH_2SO_{4\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
\(mH_2SO_{4\left(dư\right)}=0,1.98=9,8\left(g\right)\)
c1:
\(m\left(muối\right)=mCuSO_4=0,1.160=16\left(g\right)\)
c2:
\(mH_2O=0,1.18=1,8\left(g\right)\)
BTKL:
mCuO+mH2SO4 = m CuSO4+ mH2O
8 + (19,6-9,8) = m CuSO4 + 1, 8
=> mCuSO4 = 8 + ( 19,6 - 9,8 ) - 1,8 = 16 (g)
a) Cu + 2H2SO4 → CuSO4 + SO2↑ + 2H2O
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{SO_2}=n_{Cu}=0,2\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
\(\%m_{Cu}=\dfrac{12,8}{20,8}.100=61,54\%\); \(\%m_{CuO}=38,46\%\)
b) \(n_{CuO}=\dfrac{20,8-12,8}{80}=0,1\left(mol\right)\)
\(n_{H_2SO_4}=0,2.2+0,1=0,5\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,5.98}{80\%}=61,25\left(g\right)\)
\(n_{CuSO_4}=0,2+0,1=0,3\left(mol\right)\)
\(m_{CuSO_4}=0,3.160=48\left(g\right)\)
\(n_{CuO}=\dfrac{40}{80}=0,5(mol)\\ PTHH:CuO+2HCl\to CuCl_2+H_2O\\ \Rightarrow n_{CuCl_2}=n_{CuO}=0,5(mol)\\ \Rightarrow m_{CuCl_2}=0,5.135=67,5(g)\)
\(n_{Zn}=\dfrac{19.5}{65}=0.3\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)
\(n_{CuO}=\dfrac{36}{80}=0.45\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.3.....................................0.3\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(0.3.......0.3.....0.3....0.3\)
\(m_{Cr}=m_{CuO\left(dư\right)}+m_{Cu}=\left(0.45-0.3\right)\cdot80+0.3\cdot64=31.2\left(g\right)\)
\(m_{H_2O}=0.3\cdot18=5.4\left(g\right)\)
Chúc em học tốt !!
Zn+H2SO4→ZnSO4+H2 bạn biến đổi nó ra phương trình này kiểu gì vậy?
Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
____0,5____________0,5 (mol)
a, \(m_{CuCl_2}=0,5.135=67,5\left(g\right)\)
b, Có: m dd sau pư = mCuO + m dd HCl = 40 + 200 = 240 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{67,5}{240}.100\%=28,125\%\)
Bạn tham khảo nhé!
nH2 = 6.72 / 22.4 = 0.3 (mol)
Mg + H2SO4 => MgSO4 + H2
0.3.......0.3.............0.3........0.3
mMg = 0.3 * 24 = 7.2 (g)
mH2SO4 = 0.3 * 98 = 29.4 (g)
mddH2SO4 = 29.4 * 100 / 19.6 = 150 (g)
mMgSO4 = 0.3 * 120 = 36 (g)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\)
1 2 1 1
0,05 0,1 0,05 0,05
a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\)
b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.
Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
b, Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,25}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,25-0,2=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO\left(dư\right)}=0,05.80=4\left(g\right)\)
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Ta có: \(n_{H_2sO_4}=\dfrac{122,5\cdot40\%}{98}=0,5\left(mol\right)=n_{CuO}=n_{CuSO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuSO_4}=0,5\cdot160=80\left(g\right)\\m_{CuO}=0,5\cdot80=40\left(g\right)\end{matrix}\right.\)