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\(a,PTHH:KHCO_3+2H_2SO_4\rightarrow K_2SO_4+2CO_2\uparrow+2H_2O\\ b,n_{KHCO_3}=\dfrac{20}{100}=0,2\left(mol\right)\\ \Rightarrow n_{CO_2}=2n_{KHCO_3}=0,4\left(mol\right)\\ \Rightarrow V_{CO_2}=0,4\cdot22,4=8,9\left(l\right)\\ c,n_{H_2SO_4}=n_{CO_2}=0,4\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,4\cdot98=39,2\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{39,2\cdot100\%}{19,6\%}=200\left(g\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Fe có số mol là \(n_{Fe}=\frac{m}{M}=\frac{11,2}{56}=0,2mol\)
\(H_2SO_4\) có số mol là \(n_{H_2SO_4}=\frac{0,2.1}{1}=0,2mol\)
Có \(V=200ml=0,2l\)
\(\rightarrow C_M=\frac{n_{H_2SO_4}}{V_{H_2SO_4}}=\frac{0,2}{0,2}=1M\)
FeSO\(_4\) có số mol là \(n_{FeSO_4}=\frac{0,2.1}{1}=0,2mol\)
Thể tích của \(FeSO_4\) là \(V_{FeSO_4}=V_{H_2SO_4}\rightarrow C_M=\frac{n}{V}=\frac{0,2}{0,2}=1M\)
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)
FeO+H2SO4------->FeSO4+ H2
nFeO=7,2/72=0,1 (mol)
---->nH2SO4=0,1 mol
----->mH2SO4=0,1.98=9,8(g)
---->mdung dich H2SO4=(9,8.100)/49=20(g)
--->Vdung dịch H2SO4=20/1,35=14,8(l)
2NaOH+H2SO4------>Na2SO4+2H2O
nNaOH=2.0,1=0,2(mol)
---->Vnaoh=0,2/1=0,2l
1)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
____0,1----->0,15
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%=\dfrac{14,7}{250}.100\%=5,88\%\)
2)
\(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
_______0,2------------------------------>0,2
=> VCO2 = 0,2.22,4 = 4,48(l)
3)
\(n_A=\dfrac{18,4}{M_A}\left(mol\right)\)
PTHH: 2A + Cl2 --to--> 2ACl
____\(\dfrac{18,4}{M_A}\)---------->\(\dfrac{18,4}{M_A}\)
=> \(\dfrac{18,4}{M_A}\left(M_A+35,5\right)=46,8=>M_A=23\left(Na\right)\)
4)
nHCl = 0,2.3 = 0,6(mol)
PTHH: M + 2HCl --> MCl2 + H2
____0,3<-----0,6
=> \(M_M=\dfrac{7,2}{0,3}=24\left(Mg\right)\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
_____0,1----->0,15
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%=\dfrac{14,7}{250}.100\%=5,88\%\)
\(n_{Fe_2O_3}=0,2(mol)\\ Fe_2O_3+6HCl \to 2FeCl_3+3H_2O\\ n_{HCl}=1,2(mol)\\ V_{ddHCl}=\frac{250}{1,25}=200(ml)=0,2(l)\\ CM_{HCl}=\frac{1,2}{0,2}=6M$\)