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a. \(n_{Fe}=\dfrac{11.2}{56}=0,2\left(mol\right)\)
PTHH : 3Fe + 2O2 ---to---> Fe3O4
0,2 \(\dfrac{0.4}{3}\)
b. \(V_{O_2}=\dfrac{0.4}{3}.22,4=\dfrac{8.96}{3}\left(l\right)\)
c. PTHH : 2KClO3 -> 2KCl + 3O2
\(\dfrac{0.8}{3}\) \(\dfrac{0.4}{3}\)
\(m_{KClO_3}=\dfrac{0.8}{3}.122,5=\dfrac{98}{3}\left(g\right)\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a) PTHH: \(Zn+\dfrac{1}{2}O_2\xrightarrow[]{t^o}ZnO\)
b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\) \(\Rightarrow n_{O_2}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
c) PTHH: \(KClO_3\xrightarrow[MnO_2]{t^o}KCl+\dfrac{3}{2}O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,1\left(mol\right)\) \(\Rightarrow m_{KClO_3}=0,1\cdot122,5=12,25\left(g\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -t°-> 2P2O5
0,1---> 0,125--->0,05
VO2 = 0,125 . 22,4 = 2,8 (l)
mP2O5 = 0,05 . 142 = 7,1 (g)
\(n_P=\dfrac{3,1}{31}=0,1mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,1 0,125 0,05
\(V_{O_2}=0,125\cdot22,4=2,8l\)
\(m_{P_2O_5}=0,05\cdot142=7,1g\)
\(a,n_{Fe}=\dfrac{2,52}{56}=0,45\left(mol\right)\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....0,45\rightarrow0,3...0,15\\ b,V_{O_2}=0,3.22,4=6,72\left(l\right)\\ c,PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ \left(mol\right).......0,2\leftarrow............0,3\\ m_{KClO_3}=0,2.122,5=24,5\left(g\right)\)
a) 3Fe + 2O2 -> Fe3O4 ( cần thêm đk nhiệt độ ở mũi tên )
b) nFe= 25,2/56=0,45(mol)
nO2= 2/3 . nFe = 2/3 . 0,45 = 0,3 ( mol )
-> VO2 = 0,3.22,4= 6,72(lít )
c) 2KClO3 -> 2KCl + 3O2 ( cần đk nhiệt độ )
nO2 = 0,3 ( mol )
nKClO3 = 2/3 . nO2 = 2/3 . 0,3 = 0,2 ( mol)
mKClO3= 0,2 . 122,5 = 24,5(g)
Câu 3.
a)\(n_{Fe}=\dfrac{12,6}{56}=0,225mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,225 0,15 0,075
\(V_{O_2}=0,15\cdot22,4=3,36l\)
b)\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
0,1 0,15
\(m_{KClO_3}=0,1\cdot122,5=12,25g\)
c)\(n_S=\dfrac{12,8}{32}=0,4mol\)
\(S+O_2\underrightarrow{t^o}SO_2\)
0,4 0,15 0
0,15 0,15 0,15
0,25 0 0,15
\(m_{Sdư}=0,25\cdot32=8g\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
Theo pt: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}\cdot0,1=\dfrac{1}{15}mol\)
\(\Rightarrow V_{O_2}=\dfrac{1}{15}\cdot22,4=1,5l\)
Cũng theo pt: \(n_{Fe_3O_4}=\dfrac{1}{3}\cdot0,1=\dfrac{1}{30}mol\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7,73g\)