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a) \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O --> 2NaOH
_____0,125------------->0,25
\(C_{M\left(NaOH\right)}=\dfrac{0,25}{0,25}=1M\)
b)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
_______0,25---->0,125
=> mH2SO4 = 0,125.98 = 12,25(g)
=> \(m_{dd}=\dfrac{12,25.100}{20}=61,25\left(g\right)\)
BaO+H2O -> Ba(OH)2
0,02 0,02
a) CM = n/V = 0,02/0,02 = 1M
b) Ba(OH)2 + H2SO4 -> BaSO4 +2H2O
0,02 0,02
=> m = 0,392 g
D = m/V = 1,14
=> 0,392/V = 1,14 => V = 0,34l
\(n_{BaO}=\dfrac{30,6}{153}=0,2mol\)
\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
0,2 0,2
Để trung hòa: \(n_{OH^-}=n_{H^+}=0,2mol\)
\(\Rightarrow m_{HCl}=0,2\cdot36,5=7,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{7,3}{14,6}\cdot100=50\left(g\right)\)
PTHH: BaO + H2O ---> Ba(OH)2 (1)
Ba(OH)2 + 2HCl ---> BaCl2 + 2H2O (2)
Ta có: \(n_{BaO}=\dfrac{30,6}{153}=0,2\left(mol\right)\)
Theo PT(1): \(n_{Ba\left(OH\right)_2}=n_{BaO}=0,2\left(mol\right)\)
Theo PT(2): \(n_{HCl}=2.n_{Ba\left(OH\right)_2}=2.0,2=0,4\left(mol\right)\)
=> \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
Ta có: \(C_{\%_{HCl}}=\dfrac{14,6}{m_{dd_{HCl}}}.100\%=14,6\%\)
=> \(m_{dd_{HCl}}=100\left(g\right)\)
a)
$n_{Na_2O} = \dfrac{15,5}{62} = 0,25(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,5(mol)$
$C_{M_{NaOH}} = \dfrac{0,5}{0,5} = 1M$
b)
$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{H_2SO_4} = \dfrac{1}{2}n_{NaOH} = 0,25(mol)$
$\Rightarrow m_{dd\ H_2SO_4} = \dfrac{0,25.98}{20\%} = 122,5(gam)$
$\Rightarrow V_{dd\ H_2SO_4} = \dfrac{122,5}{1,14} = 107,46(ml)$
\(a,PTHH:Na_2O+H_2O\rightarrow2NaOH\\ \Rightarrow n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{37,2}{62}=0,6\cdot2=1,2\left(mol\right)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{1,2}{0,5}=2,4M\\ b,PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{58,8\cdot100\%}{20\%}=294\left(g\right)\\ \Rightarrow V_{dd}=\dfrac{294}{1,14}\approx257,9\left(ml\right)\)
