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nCuSO4.5H2O=\(\dfrac{50}{250}\)=0,2 mol
→nCuSO4=0,2(mol)
nH2O=0,2.5=1(mol)
mH2O=1.18=18(g)
VH2O=390+18=408(ml)
CMCuSO4=\(\dfrac{0,2}{0,408}=0,49M\)
mdd=50+390=440(g)
C%CuSO4=\(\dfrac{0,2.160}{440}100=7,27\%\)
tk
nCuSO4.5H2O=50/250=0,2(mol)
→→nCuSO4=0,2(mol)
nH2O=0,2.5=1(mol)
mH2O=1.18=18(g)
VH2O=390+18=408(ml)
CMCuSO4=0,2/0,408=0,49(M)
mdd=50+390=440(g)
C%CuSO4=0,2.160/440.100%=7,27%
Có: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.0,2.2=0,2\left(mol\right)\)
\(m_{dd.H_2SO_4.cần.dùng}=\dfrac{0,2.98.100\%}{20\%}=98\left(g\right)\)
\(V_{dd.H_2SO_4.cần.dùng}=\dfrac{98}{1,14}=85,96\left(ml\right)\)
Bài 4:
PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
a) Ta có: \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,5\left(mol\right)\)
\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b) Theo PTHH: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,25\cdot98}{20\%}=122,5\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
\(n_{H_2SO_4}=40\%.50=20\left(g\right)\\ Gọi:a=m_{H_2O\left(thêm\right)}\\ \Rightarrow\dfrac{20}{50+a}.100\%=10\%\\ \Leftrightarrow a=150\left(g\right)\\ \Rightarrow V_{H_2O\left(thêm\right)}=\dfrac{150}{1}=150\left(ml\right)\)